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Machine Learning Dramatically Streamlines Search for More Efficient Chemical Reactions

A catalytic reaction may follow thousands of possible paths, and it can take years to identify which one it actually takes so scientists can tweak it and make it more efficient. Now researchers at the Department of Energy's SLAC National Accelerator Laboratory and Stanford University have taken a big step toward cutting through this thicket of possibilities.

Freezing Lithium Batteries May Make Them Safer and Bendable

Columbia Engineering Professor Yuan Yang has developed a new method that could lead to lithium batteries that are safer, have longer battery life, and are bendable, providing new possibilities such as flexible smartphones. His new technique uses ice-templating to control the structure of the solid electrolyte for lithium batteries that are used in portable electronics, electric vehicles, and grid-level energy storage. The study is published online April 24 in Nano Letters.

New Study Reveals the Mystery Behind the Formation of Hollowed Nanoparticles During Metal Oxidation

In a newly published <i>Science</i> paper, Argonne and Temple University researchers reveal new knowledge about the behavior of metal nanoparticles when they undergo oxidation, by integrating X-ray imaging and computer modeling and simulation. This knowledge adds to our understanding of fundamental processes like oxidation and corrosion.

Rare Supernova Discovery Ushers in New Era for Cosmology

With help from a supernova-hunting pipeline based at NERSC, astronomers captured multiple images of a gravitationally lensed Type 1a supernova. This is currently the only one, but if astronomers can find more they may be able to measure Universal expansion within four percent accuracy. Luckily, Berkeley Lab researchers do have a method for finding more.

Making Batteries From Waste Glass Bottles

Researchers at the University of California, Riverside's Bourns College of Engineering have used waste glass bottles and a low-cost chemical process to create nanosilicon anodes for high-performance lithium-ion batteries. The batteries will extend the range of electric vehicles and plug-in hybrid electric vehicles, and provide more power with fewer charges to personal electronics like cell phones and laptops.

Changing the Game

High performance computing researcher Shuaiwen Leon Song asked if hardware called 3D stacked memory could do something it was never designed to do--help render 3D graphics.

A Scientific Advance for Cool Clothing: Temperature-Wise, That Is

Stanford University researchers, with the aid of the Comet supercomputer at the San Diego Supercomputer at UC San Diego, have engineered a low-cost plastic material that could become the basis for clothing that cools the wearer, reducing the need for energy-consuming air conditioning.

Adjusting Solar Panel Angles a Few Times a Year Makes Them More Efficient

With Earth Day approaching, new research from Binghamton University-State of New York could help U.S. residents save more energy, regardless of location, if they adjust the angles of solar panels four to five times a year.

A Real CAM-Do Attitude

A multi-institutional team used resources at the Oak Ridge Leadership Computing Facility to catalog how desert plants photosynthetic processes vary. The study could help scientists engineer drought-resistant crops for food and fuel.

Predictive Power

The Consortium for Advanced Simulation of Light Water Reactors carried out the largest time-dependent simulation of a nuclear reactor ever to support Tennessee Valley Authority and Westinghouse Electric Company during the startup of Watts Bar Unit 2, the first new US nuclear reactor in 20 years. The simulation was carried out primarily on OLCF resources.


3 Small Energy Firms to Collaborate with PNNL

Pacific Northwest National Laboratory is collaborating with three small businesses to address technical challenges concerning hydrogen for fuel cell cars, bio-coal and nanomaterial manufacturing.

ORNL to Collaborate with Five Small Businesses to Advance Energy Tech

Five small companies have been selected to partner with the Department of Energy's Oak Ridge National Laboratory to move technologies in commercial refrigeration systems, water power generation, bioenergy and battery manufacturing closer to the marketplace.

U.S. Department of Energy's INCITE Program Seeks Advanced Computational Research Proposals for 2018

The Department of Energy's INCITE program will be accepting proposals for high-impact, computationally intensive research campaigns in a broad array of science, engineering, and computer science domains.

New Berkeley Lab Project Turns Waste Heat to Electricity

A new Berkeley Lab project seeks to efficiently capture waste heat and convert it to electricity, potentially saving California up to $385 million per year. With a $2-million grant from the California Energy Commission, Berkeley Lab scientists will work with Alphabet Energy to create a cost-effective thermoelectric waste heat recovery system.

New SLAC Theory Institute Aims to Speed Research on Exotic Materials at Light Sources

A new institute at the Department of Energy's SLAC National Accelerator Laboratory is using the power of theory to search for new types of materials that could revolutionize society - by making it possible, for instance, to transmit electricity over power lines with no loss.

Lenvio Inc. Exclusively Licenses ORNL Malware Behavior Detection Technology

Virginia-based Lenvio Inc. has exclusively licensed a cyber security technology from the Department of Energy's Oak Ridge National Laboratory that can quickly detect malicious behavior in software not previously identified as a threat.

Argonne Scientist and Nobel Laureate Alexei Abrikosov Dies at 88

Alexei Abrikosov, an acclaimed physicist at the U.S. Department of Energy's Argonne National Laboratory who received the 2003 Nobel Prize in Physics for his work on superconducting materials, died Wednesday, March 29. He was 88.

Jefferson Lab Accomplishes Critical Milestones Toward Completion of 12 GeV Upgrade

The Continuous Electron Beam Accelerator Facility (CEBAF) at the U.S. Department of Energy's Thomas Jefferson National Accelerator Facility has achieved two major commissioning milestones and is now entering the final stretch of work to conclude its first major upgrade. Recently, the CEBAF accelerator delivered electron beams into two of its experimental halls, Halls B and C, at energies not possible before the upgrade for commissioning of the experimental equipment currently in each hall. Data were recorded in each hall, which were then confirmed to be of sufficient quality to allow for particle identification, a primary indicator of good detector operation.

Valerie Taylor Named Argonne National Laboratory's Mathematics and Computer Science Division Director

Computer scientist Valerie Taylor has been appointed as the next director of the Mathematics and Computer Science division at Argonne, effective July 3, 2017.

Three SLAC Employees Awarded Lab's Highest Honor

At a March 7 ceremony, three employees of the Department of Energy's SLAC National Accelerator Laboratory were awarded the lab's highest honor ­- the SLAC Director's Award.


The Roadmap to Quark Soup

Scientists discover new signposts in the quest to determine how matter from the early universe turned into the world we know today.

Neutrons Play the Lead to Protons in Dance Around "Double-Magic" Nucleus

Electric and magnetic properties of a radioactive atom provide unique insight into the nature of proton and neutron motion.

Ultrafast Imaging Reveals the Electron's New Clothes

Scientists use high-speed electrons to visualize "dress-like" distortions in the atomic lattice. This work reveals the vital role of electron-lattice interactions in manganites. This material could be used in data-storage devices with increased data density and reduced power requirements.

One Small Change Makes Solar Cells More Efficient

For years, scientists have explored using tiny drops of designer materials, called quantum dots, to make better solar cells. Adding small amounts of manganese decreases the ability of quantum dots to absorb light but increases the current produced by an average of 300%.

Electronic "Cyclones" at the Nanoscale

Through highly controlled synthesis, scientists controlled competing atomic forces to let spiral electronic structures form. These polar vortices can serve as a precursor to new phenomena in materials. The materials could be vital for ultra-low energy electronic devices.

In a Flash! A New Way for Making Ceramics

A new process controllably but instantly consolidates ceramic parts, potentially important for manufacturing.

Deciphering Material Properties at the Single-Atom Level

Scientists determine the precise location and identity of all 23,000 atoms in a nanoparticle.

Smallest Transistor Ever

It has long been thought that building nanometer-sized transistors was impossible. Simply put, the physics and atomic structural imperfections couldn't be overcome. However, scientists built fully functional, nanometer-sized transistors.

Creation of Artificial Atoms

For the first time, scientists created a tunable artificial atom in graphene. The results from this research demonstrate a viable, controllable, and reversible technique to confine electrons in graphene.

Developing Tools to Understand Lithium-Ion Battery Instabilities

Scientists develop tools to understand Li-ion battery instabilities, enabling the study of electrodes and solid-electrolyte interphase formation.


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Self-Charging Power Cell Converts and Stores Energy

Article ID: 592810

Released: 2012-08-21 14:00:00

Source Newsroom: Georgia Institute of Technology, Research Communications

  • Credit: Georgia Tech Photo: Gary Meek

    Georgia Tech researcher Zhong Lin Wang holds the components of a new self-charging power cell that uses piezoelectric materials to directly convert mechanical energy to chemical energy. The chemical energy can be released as electricity.

  • Credit: Georgia Tech Photo: Gary Meek

    Georgia Tech professor Zhong Lin Wang (left) and Ph.D. candidate Sihong Wang hold components of a new self-charging power cell that uses piezoelectric materials to directly convert mechanical energy to chemical energy. The chemical energy can be released as electricity.

  • Credit: Georgia Tech Photo: Gary Meek

    Georgia Tech researcher Zhong Lin Wang holds the components of a new self-charging power cell that uses piezoelectric materials to directly convert mechanical energy to chemical energy. The chemical energy can be released as electricity.

Researchers have developed a self-charging power cell that directly converts mechanical energy to chemical energy, storing the power until it is released as electrical current. By eliminating the need to convert mechanical energy to electrical energy for charging a battery, the new hybrid generator-storage cell utilizes mechanical energy more efficiently than systems using separate generators and batteries.

At the heart of the self-charging power cell is a piezoelectric membrane that drives lithium ions from one side of the cell to the other when the membrane is deformed by mechanical stress. The lithium ions driven through the polarized membrane by the piezoelectric potential are directly stored as chemical energy using an electrochemical process.

By harnessing a compressive force, such as a shoe heel hitting the pavement from a person walking, the power cell generates enough current to power a small calculator. A hybrid power cell the size of a conventional coin battery can power small electronic devices – and could have military applications for soldiers who might one day recharge battery-powered equipment as they walked.

“People are accustomed to considering electrical generation and storage as two separate operations done in two separate units,” said Zhong Lin Wang, a Regents professor in the School of Materials Science and Engineering at the Georgia Institute of Technology. “We have put them together in a single hybrid unit to create a self-charging power cell, demonstrating a new technique for charge conversion and storage in one integrated unit.”

The research was reported Aug. 9, 2012 in the journal Nano Letters. The research was supported by the Defense Advanced Research Projects Agency (DARPA), the U.S. Air Force, the U.S. Department of Energy, the National Science Foundation, and the Knowledge Innovation Program of the Chinese Academy of Sciences.

The power cell consists of a cathode made from lithium-cobalt oxide (LiCoO2) and an anode consisting of titanium dioxide (TiO2) nanotubes grown atop a titanium film. The two electrodes are separated by a membrane made from poly(vinylidene fluoride) (PVDF) film, which generates a piezoelectric charge when placed under strain. When the power cell is mechanically compressed, the PVDF film generates a piezoelectric potential that serves as a charge pump to drive the lithium ions from the cathode side to the anode side. The energy is then stored in the anode as lithium-titanium oxide.

Charging occurs in cycles with the compression of the power cell creating a piezopotential that drives the migration of lithium ions until a point at which the chemical equilibrium of the two electrodes are re-established and the distribution of lithium ions can balance the piezoelectric fields in the PVDF film. When the force applied to the power cell is released, the piezoelectric field in the PVDF disappears, and the lithium ions are kept at the anode through a chemical process.

The charging cycle is completed through an electrochemical process that oxidizes a small amount of lithium-cobalt oxide at the cathode to Li1-xCoO2 and reduces a small amount of titanium dioxide to LixTiO2 at the anode. Compressing the power cell again repeats the cycle.

When an electrical load is connected between the anode and cathode, electrons flow to the load, and the lithium ions within the cell flow back from the anode side to the cathode side.

Using a mechanical compressive force with a frequency of 2.3 Hertz, the researchers increased the voltage in the power cell from 327 to 395 millivolts in just four minutes. The device was then discharged back to its original voltage with a current of one milliamp for about two minutes. The researchers estimated the stored electric capacity of the power cell to be approximately 0.036 milliamp-hours.

So far, Wang and his research team – which included Xinyu Xue, Sihong Wang, Wenxi Guo and Yan Zhang – have built and tested more than 500 of the power cells. Wang estimates that the generator-storage cell will be as much as five times more efficient at converting mechanical energy to chemical energy for as a two-cell generator-storage system.

Much of the mechanical energy applied to the cells is now consumed in deforming the stainless steel case the researchers are using to house their power cell. Wang believes the power storage could be boosted by using an improved case.

“When we improve the packaging materials, we anticipate improving the overall efficiency,” he said. “The amount of energy actually going into the cell is relatively small at this stage because so much of it is consumed by the shell.”

Beyond the efficiencies that come from directly converting mechanical energy to chemical energy, the power cell could also reduce weight and space required by separate generators and batteries. The mechanical energy could come from walking, the tires of a vehicle hitting the pavement, or by harnessing ocean waves or mechanical vibrations.

“One day we could have a power package ready to use that takes advantage of this hybrid approach,” Wang said. “Almost anything that involves mechanical action could provide the strain needed for charging. People walking could be generating electricity as they move.”

This research was supported by DARPA (HR0011-09-C-0142); the U.S. Air Force, the U.S. Department of Energy, Office of Basic Energy Sciences (DE-FG02-07ER46394), the National Science Foundation (CMMI-0403671), and the Knowledge Innovation Program of the Chinese Academy of Sciences (KJCX2-YW-M13). The content is solely the responsibility of the authors and does not necessarily represent the official views of DARPA, the U.S. Air Force, the Department of Energy or the National Science Foundation.

Citation: Xinyu Xue, Sihong Wang, Wenxi Guo, Yan Zhang and Zhong Lin Wang, Hybridizing Energy Conversion and Storage in a Mechanical-to-Electrochemical Process for Self-Charging Power Cell, Nano Letters. DOI: 10.1021/nl302879t

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Media Relations Contact: John Toon (404-894-6986)(jtoon@gatech.edu).

Writer: John Toon