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Chemists ID Catalytic 'Key' for Converting CO2 to Methanol

Results from experiments and computational modeling studies that definitively identify the "active site" of a catalyst commonly used for making methanol from CO2 will guide the design of improved catalysts for transforming this pollutant to useful chemicals.

Cryo-Electron Microscopy Achieves Unprecedented Resolution Using New Computational Methods

Cryo-electron microscopy (cryo-EM)--which enables the visualization of viruses, proteins, and other biological structures at the molecular level--is a critical tool used to advance biochemical knowledge. Now Berkeley Lab researchers have extended cryo-EM's impact further by developing a new computational algorithm instrumental in constructing a 3-D atomic-scale model of bacteriophage P22 for the first time.

New Study Maps Space Dust in 3-D

A new Berkeley Lab-led study provides detailed 3-D views of space dust in the Milky Way, which could help us understand the properties of this dust and how it affects views of distant objects.

Single-Angle Ptychography Allows 3D Imaging of Stressed Materials

Scientists have used a new X-ray diffraction technique called Bragg single-angle ptychography to get a clear picture of how planes of atoms shift and squeeze under stress.

New Feedback System Could Allow Greater Control Over Fusion Plasma

A physicist has created a new system that will let scientists control the energy and rotation of plasma in real time in a doughnut-shaped machine known as a tokamak.

Towards Super-Efficient, Ultra-Thin Silicon Solar Cells

Researchers from Ames Laboratory used supercomputers at NERSC to evaluate a novel approach for creating more energy-efficient ultra-thin crystalline silicon solar cells by optimizing nanophotonic light trapping.

Study IDs Link Between Sugar Signaling and Regulation of Oil Production in Plants

UPTON, NY--Even plants have to live on an energy budget. While they're known for converting solar energy into chemical energy in the form of sugars, plants have sophisticated biochemical mechanisms for regulating how they spend that energy. Making oils costs a lot. By exploring the details of this delicate energy balance, a group of scientists from the U.

High-Energy Electrons Probe Ultrafast Atomic Motion

A new technique synchronized high-energy electrons with an ultrafast laser pulse to probe how vibrational states of atoms change in time.

Rare Earth Recycling

A new energy-efficient separation of rare earth elements could provide a new domestic source of critical materials.

Two-Dimensional MXene Materials Get Their Close-Up

Researchers have long sought electrically conductive materials for economical energy-storage devices. Two-dimensional (2D) ceramics called MXenes are contenders.


Three SLAC Employees Awarded Lab's Highest Honor

At a March 7 ceremony, three employees of the Department of Energy's SLAC National Accelerator Laboratory were awarded the lab's highest honor ­- the SLAC Director's Award.

Dan Sinars Represents Sandia in First Energy Leadership Class

Dan Sinars, a senior manager in Sandia National Laboratories' pulsed power center, which built and operates the Z facility, is the sole representative from a nuclear weapons lab in a new Department of Energy leadership program that recently visited Sandia.

ORNL, HTS International Corporation to Collaborate on Manufacturing Research

HTS International Corporation and the Department of Energy's Oak Ridge National Laboratory have signed an agreement to explore potential collaborations in advanced manufacturing research.

Jefferson Lab Director Honored with Energy Secretary Award

Hugh Montgomery, director of the Department of Energy's Thomas Jefferson National Accelerator Facility (Jefferson Lab), was awarded The Secretary's Distinguished Service Award by the Secretary of Energy earlier this year.

New Projects to Make Geothermal Energy More Economically Attractive

Geothermal energy, a clean, renewable source of energy produced by the heat of the earth, provides about 6 percent of California's total power. That number could be much higher if associated costs were lower. Now scientists at the Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) have launched two California Energy Commission-funded projects aimed at making geothermal energy more cost-effective to deploy and operate.

Southern Research Project Advances Novel CO2 Utilization Strategy

The U.S. Department of Energy's Office of Fossil Energy has awarded Southern Research nearly $800,000 for a project that targets a more cost-efficient and environmentally friendly method of producing some of the most important chemicals used in manufacturing.

Harker School Wins 2017 SLAC Regional Science Bowl Competition

After losing its first match of the day to the defending champions, The Harker School's team won 10 consecutive rounds to claim victory in the annual SLAC Regional DOE Science Bowl on Saturday, Feb. 11.

Francis Alexander Named Deputy Director of Brookhaven Lab's Computational Science Initiative

Alexander brings extensive management and leadership experience in computational science research to the position.

Kalinin, Paranthaman Elected Materials Research Society Fellows

Two researchers at Oak Ridge National Laboratory, Sergei Kalinin and Mariappan Parans Paranthaman, have been elected fellows of the Materials Research Society.

Two PNNL Researchers Elected to Membership in the National Academy of Engineering

Two scientists at the Pacific Northwest National Laboratory will become members of the prestigious National Academy of Engineering.


High-Energy Electrons Probe Ultrafast Atomic Motion

A new technique synchronized high-energy electrons with an ultrafast laser pulse to probe how vibrational states of atoms change in time.

Rare Earth Recycling

A new energy-efficient separation of rare earth elements could provide a new domestic source of critical materials.

Modeling the "Flicker" of Gluons in Subatomic Smashups

A new model identifies a high degree of fluctuations in the glue-like particles that bind quarks within protons as essential to explaining proton structure.

Rare Nickel Atom Has "Doubly Magic" Structure

Supercomputing calculations confirm that rare nickel-78 has unusual structure, offering insights into supernovas.

Microbial Activity in the Subsurface Contributes to Greenhouse Gas Fluxes

Natural carbon dioxide production from deep subsurface soils contributes significantly to emissions, even in a semiarid floodplain.

Stretching a Metal Into an Insulator

Straining a thin film controllably allows tuning of the materials' magnetic, electronic, and catalytic properties, essential for new energy and electronic devices.

How Moisture Affects the Way Soil Microbes Breathe

Study models soil-pore features that hold or release carbon dioxide.

ARM Data Is for the Birds

Scientists use LIDAR and radar data to study bird migration patterns, thanks to the Atmospheric Radiation Measurement (ARM) Climate Research Facility.

The Future of Coastal Flooding

Better storm surge prediction capabilities could help reduce the impacts of extreme weather events, such as hurricanes.

Estimating Global Energy Use for Water-Related Processes

Scientists find that water-related energy consumption is increasing across the globe, with pronounced differences across regions and sectors.


Friday March 24, 2017, 10:40 AM

Great Neck South High School Wins Regional Science Bowl at Brookhaven Lab

Brookhaven National Laboratory

Wednesday February 15, 2017, 04:05 PM

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Haslam Visits ORNL to Highlight State's Role in Discovering Tennessine

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Internship Program Helps Foster Development of Future Nuclear Scientists

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More Than 12,000 Explore Jefferson Lab During April 30 Open House

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NMSU Undergrad Tackles 3D Particle Scattering Animations After Receiving JSA Research Assistantship

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Shannon Greco: A Self-Described "STEM Education Zealot"

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Meet Robert Palomino: 'Give Everything a Shot!'

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University of Utah Makes Solar Accessible

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Texas Tech Energy Commerce Students, Community Light up Tent City

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Helping a Greenhouse Gas Turn Over a New Leaf

Article ID: 613128

Released: 2014-01-30 17:00:00

Source Newsroom: University of Delaware

  • Credit: Evan Krape/University of Delaware

    A University of Delaware engineering research team led by Feng Jiao has developed a highly selective catalyst capable of electrochemically converting carbon dioxide to carbon monoxide with 92 percent efficiency.

  • Credit: Illustration courtesy of Feng Jiao/University of Delaware

    The University of Delaware's nano-porous silver electrocatalyst has an extremely large and highly curved internal surface, which is approximately 150 times larger and 20 times intrinsically more active than the polycrystalline silver commonly used in converting carbon dioxide to useful chemicals.

Andrea Boyle Tippett

aboyle@udel.edu

A team of researchers at the University of Delaware has developed a highly selective catalyst capable of electrochemically converting carbon dioxide — a greenhouse gas — to carbon monoxide with 92 percent efficiency. The carbon monoxide then can be used to develop useful chemicals.

The researchers recently reported their findings in Nature Communications.

“Converting carbon dioxide to useful chemicals in a selective and efficient way remains a major challenge in renewable and sustainable energy research,” according to Feng Jiao, assistant professor of chemical and biomolecular engineering and the project’s lead researcher.

Co-authors on the paper include Qi Lu, a postdoctoral fellow, and Jonathan Rosen, a graduate student, working with Jiao.

The researchers found that when they used a nano-porous silver electrocatalyst, it was 3,000 times more active than polycrystalline silver, a catalyst commonly used in converting carbon dioxide to useful chemicals.

Silver is considered a promising material for a carbon dioxide reduction catalyst because of it offers high selectivity — approximately 81 percent — and because it costs much less than other precious metal catalysts. Additionally, because it is inorganic, silver remains more stable under harsh catalytic environments.

The exceptionally high activity, Jiao said, is likely due to the UD-developed electrocatalyst’s extremely large and highly curved internal surface, which is approximately 150 times larger and 20 times intrinsically more active than polycrystalline silver.

Jiao explained that the active sites on the curved internal surface required a much smaller than expected voltage to overcome the activation energy barrier needed drive the reaction.

The resulting carbon monoxide, he continued, can be used as an industry feedstock for producing synthetic fuels, while reducing industrial carbon dioxide emissions by as much as 40 percent.

To validate whether their findings were unique, the researchers compared the UD-developed nano-porous silver catalyst with other potential carbon dioxide electrocatalysts including polycrystalline silver and other silver nanostructures such as nanoparticles and nanowires.

Testing under identical conditions confirmed the non-porous silver catalyst’s significant advantages over other silver catalysts in water environments.

Reducing greenhouse carbon dioxide emissions from fossil fuel use is considered critical for human society. Over the last 20 years, electrocatalytic carbon dioxide reduction has attracted attention because of the ability to use electricity from renewable energy sources such as wind, solar and wave.

Ideally, Jiao said, one would like to convert carbon dioxide produced in power plants, refineries and petrochemical plants to fuels or other chemicals through renewable energy use.

A 2007 Intergovernmental Panel on Climate Change report stated that 19 percent of greenhouse gas emissions resulted from industry in 2004, according to the Environmental Protection Agency’s website.

“Selective conversion of carbon dioxide to carbon monoxide is a promising route for clean energy but it is a technically difficult process to accomplish,” said Jiao. “We’re hopeful that the catalyst we’ve developed can pave the way toward future advances in this area.”

The research team’s work is supported through funding from the American Chemical Society Petroleum Research Fund and University of Delaware Research Foundation. Jiao has patented the novel application technique in collaboration with UD’s Office of Economic Innovation and Partnerships.

About the professor

Feng Jiao joined UD in 2010. In addition to his faculty role in chemical and biomolecular engineering, he is also affiliated with the Center for Catalytic Science and Technology.

His research interests include developing clean, sustainable and environmental friendly energy supplies by combining catalysis, materials science and electrochemistry to address current energy conversion and storage challenges.

Jiao’s previous work includes developing novel cathode materials to boost the energy storage of lithium-ion batteries, which are used in items ranging from laptops to electric cars, through a new synthetic method, ionothermal synthesis, for preparing lithium manganese phosphates with 3D nanoporous structures.