Doe Science news source
The DOE Science News Source is a Newswise initiative to promote research news from the Office of Science of the DOE to the public and news media.
  • 2016-12-22 11:05:32
  • Article ID: 666932

Researchers Use World's Smallest Diamonds to Make Wires Three Atoms Wide

LEGO-style Building Method Has Potential for Making One-Dimensional Materials with Extraordinary Properties

  • Credit: SLAC National Accelerator Laboratory

    This animation shows molecular building blocks joining the tip of a growing nanowire. Each block consists of a diamondoid – the smallest possible bit of diamond – attached to sulfur and copper atoms (yellow and brown spheres). Like LEGO blocks, they only fit together in certain ways that are determined by their size and shape. The copper and sulfur atoms form a conductive wire in the middle, and the diamondoids form an insulating outer shell.

  • Credit: SEM image by Hao Yan/SIMES; photo by SLAC National Accelerator Laboratory

    Fuzzy white clusters of nanowires on a lab bench, with a penny for scale. Assembled with the help of diamondoids, the microscopic nanowires can be seen with the naked eye because the strong mutual attraction between their diamondoid shells makes them clump together, in this case by the millions. At top right, an image made with a scanning electron microscope shows nanowire clusters magnified 10,000 times.

  • Credit: H. Yan et al., Nature Materials

    An illustration shows a hexagonal cluster of seven nanowires assembled by diamondoids. Each wire has an electrically conductive core made of copper and sulfur atoms (brown and yellow spheres) surrounded by an insulating diamondoid shell. The natural attraction between diamondoids drives the assembly process.

  • Credit: SLAC National Accelerator Laboratory

    An illustration shows the basic nanowire building block – a diamondoid cage carrying atoms of copper and sulfur – drifting toward the growing tip of a nanowire, center, where it will attach in a way determined by its size and shape. The copper and sulfur atoms wind up on the inside, forming a core of semiconducting material, and the diamondoids remain on the outside, where they function as an insulating shell.

  • Credit: SLAC National Accelerator Laboratory

    Stanford graduate student Fei Hua Li, left, and postdoctoral researcher Hao Yan in one of the SIMES labs where diamondoids – the tiniest bits of diamond – were used to assemble the thinnest possible nanowires.

  • Credit: SLAC National Accelerator Laboratory

    Ball-and-stick models of diamondoid atomic structures in the SIMES lab at SLAC. SIMES researchers used the smallest possible diamondoid – adamantane, a tiny cage made of 10 carbon atoms – to assemble the smallest possible nanowires, with conductive cores just three atoms wide.

Menlo Park, Calif. — Scientists at Stanford University and the Department of Energy’s SLAC National Accelerator Laboratory have discovered a way to use diamondoids – the smallest possible bits of diamond – to assemble atoms into the thinnest possible electrical wires, just three atoms wide.

By grabbing various types of atoms and putting them together LEGO-style, the new technique could potentially be used to build tiny wires for a wide range of applications, including fabrics that generate electricity, optoelectronic devices that employ both electricity and light, and superconducting materials that conduct electricity without any loss. The scientists reported their results today in Nature Materials.

“What we have shown here is that we can make tiny, conductive wires of the smallest possible size that essentially assemble themselves,” said Hao Yan, a Stanford postdoctoral researcher and lead author of the paper. “The process is a simple, one-pot synthesis. You dump the ingredients together and you can get results in half an hour. It’s almost as if the diamondoids know where they want to go.”

The Smaller the Better

Although there are other ways to get materials to self-assemble, this is the first one shown to make a nanowire with a solid, crystalline core that has good electronic properties, said study co-author Nicholas Melosh, an associate professor at SLAC and Stanford and investigator with SIMES, the Stanford Institute for Materials and Energy Sciences at SLAC.

The needle-like wires have a semiconducting core – a combination of copper and sulfur known as a chalcogenide – surrounded by the attached diamondoids, which form an insulating shell.

Their minuscule size is important, Melosh said, because a material that exists in just one or two dimensions – as atomic-scale dots, wires or sheets – can have very different, extraordinary properties compared to the same material made in bulk. The new method allows researchers to assemble those materials with atom-by-atom precision and control.

The diamondoids they used as assembly tools are tiny, interlocking cages of carbon and hydrogen. Found naturally in petroleum fluids, they are extracted and separated by size and geometry in a SLAC laboratory. Over the past decade, a SIMES research program led by Melosh and SLAC/Stanford Professor Zhi-Xun Shen has found a number of potential uses for the little diamonds, including improving electron microscope images and making tiny electronic gadgets.

Constructive Attraction

For this study, the research team took advantage of the fact that diamondoids are strongly attracted to each other, through what are known as van der Waals forces. (This attraction is what makes the microscopic diamondoids clump together into sugar-like crystals, which is the only reason you can see them with the naked eye.)

They started with the smallest possible diamondoids – single cages that contain just 10 carbon atoms – and attached a sulfur atom to each. Floating in a solution, each sulfur atom bonded with a single copper ion. This created the basic nanowire building block.

The building blocks then drifted toward each other, drawn by the van der Waals attraction between the diamondoids, and attached to the growing tip of the nanowire.

“Much like LEGO blocks, they only fit together in certain ways that are determined by their size and shape,” said Stanford graduate student Fei Hua Li, who played a critical role in synthesizing the tiny wires and figuring out how they grew. “The copper and sulfur atoms of each building block wound up in the middle, forming the conductive core of the wire, and the bulkier diamondoids wound up on the outside, forming the insulating shell.”

A Versatile Toolkit for Creating Novel Materials

The team has already used diamondoids to make one-dimensional nanowires based on cadmium, zinc, iron and silver, including some that grew long enough to see without a microscope, and they have experimented with carrying out the reactions in different solvents and with other types of rigid, cage-like molecules, such as carboranes.

The cadmium-based wires are similar to materials used in optoelectronics, such as light-emitting diodes (LEDs), and the zinc-based ones are like those used in solar applications and in piezoelectric energy generators, which convert motion into electricity.

“You can imagine weaving those into fabrics to generate energy,” Melosh said. “This method gives us a versatile toolkit where we can tinker with a number of ingredients and experimental conditions to create new materials with finely tuned electronic properties and interesting physics.”

Theorists led by SIMES Director Thomas Devereaux modeled and predicted the electronic properties of the nanowires, which were examined with X-rays at SLAC’s Stanford Synchrotron Radiation Lightsource, a DOE Office of Science User Facility, to determine their structure and other characteristics.

The team also included researchers from the Stanford Department of Materials Science and Engineering, Lawrence Berkeley National Laboratory, the National Autonomous University of Mexico (UNAM) and Justus-Liebig University in Germany. Parts of the research were carried out at Berkeley Lab’s Advanced Light Source (ALS) and National Energy Research Scientific Computing Center (NERSC), both DOE Office of Science User Facilities. The work was funded by the DOE Office of Science and the German Research Foundation.

SLAC is a multi-program laboratory exploring frontier questions in photon science, astrophysics, particle physics and accelerator research. Located in Menlo Park, California, SLAC is operated by Stanford University for the U.S. Department of Energy Office of Science. To learn more, please visit www.slac.stanford.edu.

SLAC National Accelerator Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov.

X
X
X
  • Filters

  • × Clear Filters

The Challenge of Estimating Alaska's Soil Carbon Stocks

A geospatial analysis determined the optimal distribution of sites needed to reliably estimate Alaska's vast soil carbon.

Strain-Free Epitaxy of Germanium Film on Mica

Germanium was the material of choice in the early history of electronic devices, and due to its high charge carrier mobility, it's making a comeback. It's generally grown on expensive single-crystal substrates, adding another challenge to making it sustainably viable for most applications. To address this aspect, researchers demonstrate an epitaxy method that incorporates van der Waals' forces to grow germanium on mica. They discuss their work in the Journal of Applied Physics.

Unplugging the Cellulose Biofuel Bottleneck

Molecular-level understanding of cellulose structure reveals why it resists degradation and could lead to cost-effective biofuels.

Detailed View of Immune Proteins Could Lead to New Pathogen-Defense Strategies

Biologists at Berkeley Lab and UC Berkeley used cryo-EM to resolve the structure of a ring of proteins used by the immune system to summon support when under attack, providing new insight into potential strategies for protection from pathogens. The researchers captured the high-resolution image of a protein ring, called an inflammasome, as it was bound to flagellin, a protein from the whiplike tail used by bacteria to propel themselves forward.

Unlocking the Secrets of Ebola

Scientists have identified a set of biomarkers that indicate which patients infected with the Ebola virus are most at risk of dying from the disease. The results come from one of the most in-depth studies ever of blood samples from patients with Ebola.

Scientists Make First Observations of How a Meteor-Like Shock Turns Silica Into Glass

Studies at the Department of Energy's SLAC National Accelerator Laboratory have made the first real-time observations of how silica - an abundant material in the Earth's crust - easily transforms into a dense glass when hit with a massive shock wave like one generated from a meteor impact.

How Fungal Enzymes Break Down Plant Cell Walls

Lignocellulose-degrading enzyme complexes could improve biofuel production.

Stretching to Perfection of 2-D Semiconductors

Scientists use heat and mismatched surfaces to stretch films that can potentially improve the efficient operation of devices.

Simple is Beautiful in Quantum Computing

Defect spins in diamond were controlled with a simpler, geometric method, leading to faster computing.

Replace or Wait? Study Says Swap All Incandescent Bulbs Now, but Hold on to CFLs, older LEDs

LED light bulbs are getting cheaper and more energy efficient every year. So, does it make sense to replace less-efficient bulbs with the latest light-emitting diodes now, or should you wait for future improvements and even lower costs?


  • Filters

  • × Clear Filters

Argonne to Install Comanche System to Explore ARM Technology for High-Performance Computing

Argonne National Laboratory is collaborating with Hewlett Packard Enterprise (HPE) to provide system software expertise and a development ecosystem for a future high-performance computing (HPC) system based on 64-bit ARM processors.

CANDLE Shines in 2017 HPCwire Readers' and Editors' Choice Awards

Argonne National Laboratory has been recognized in the annual <em>HPCwire</em> Readers' and Editors' Choice Awards, presented at the 2017 International Conference for High Performance Computing, Networking, Storage and Analysis (SC17), in Denver, Colorado.

SLAC's Helen Quinn Honored with 2018 Benjamin Franklin Medal in Physics

Helen Quinn, a professor emerita at the Department of Energy's SLAC National Accelerator Laboratory and Stanford University, will receive the 2018 Benjamin Franklin Medal in Physics - one of eight prestigious Franklin Institute Awards that will be handed out in Philadelphia next April.

PPPL Honors Grierson and Greenough for Distinguished Research and Engineering Achievements

Article describes PPPL's presentation of 2017 Kaul Prize and Distinguished Engineering Fellow awards.

INCITE Grants of 5.95 Billion Hours Awarded to 55 Computational Research Projects

The U.S. Department of Energy's Office of Science announced 55 projects with high potential for accelerating discovery through its Innovative and Novel Computational Impact on Theory and Experiment (INCITE) program. The projects will share 5.95 billion core-hours on three of America's most powerful supercomputers dedicated to capability-limited open science and support a broad range of large-scale research campaigns from infectious disease treatment to next-generation materials development.

Former SLAC Director Jonathan Dorfan Awarded Japan's Order of the Rising Sun

Former SLAC Director and Stanford University Professor Emeritus Jonathan Dorfan has been awarded Japan's Order of the Rising Sun, Gold and Silver Star for his contributions as founding president of the Okinawa Institute of Science and Technology Graduate University (OIST). It is the highest award Japan bestows on university presidents.

Jefferson Lab Staff Scientist Honored with APS Fellowship

Fulvia Pilat, a staff scientist at the Department of Energy's Thomas Jefferson National Accelerator Facility, has been named a fellow of the American Physical Society. The honor is bestowed by members of APS on their peers for exceptional contributions to their fields.

First Northwest Theoretical Chemistry Conference Is a Hit!

The first Northwest Theoretical Chemistry Conference was a success. The event offered ~50 early career theorists and students opportunities to present talks in a nurturing environment that developed and advanced collaborations.

Argonne Forms New Divisions to Focus on Computation and Data Science Strengths

Argonne has formed two new research divisions to focus its lab-wide foundational expertise on computational science and data science activities.

Hermann Grunder Recognized by IEEE Nuclear and Plasma Sciences Society

Dr. Hermann Grunder, Founding Director of Jefferson Lab, has been selected as one of two recipients of the 2018 IEEE NPSS Particle Accelerator Science and Technology (PAST) Award.


  • Filters

  • × Clear Filters

The Challenge of Estimating Alaska's Soil Carbon Stocks

A geospatial analysis determined the optimal distribution of sites needed to reliably estimate Alaska's vast soil carbon.

Unplugging the Cellulose Biofuel Bottleneck

Molecular-level understanding of cellulose structure reveals why it resists degradation and could lead to cost-effective biofuels.

How Fungal Enzymes Break Down Plant Cell Walls

Lignocellulose-degrading enzyme complexes could improve biofuel production.

Stretching to Perfection of 2-D Semiconductors

Scientists use heat and mismatched surfaces to stretch films that can potentially improve the efficient operation of devices.

Simple is Beautiful in Quantum Computing

Defect spins in diamond were controlled with a simpler, geometric method, leading to faster computing.

The Effect of Hurricanes on Puerto Rico's Dry Forests

More frequent storms turn forests from carbon source to sink.

A Chemical Thermometer for Tropical Forests

Monoterpene measures how certain forests respond to heat stress.

Where a Leaf Lands and Lies Influences Carbon Levels in Soil for Years to Come

Whether carbon comes from leaves or needles affects how fast it decomposes, but where it ends up determines how long it's available.

Twisting Molecule Wrings More Power from Solar Cells

Readily rotating molecules let electrons last, resulting in higher solar cell efficiency.

Rules Are Only Suggestions in Heavy Elements

The arrangement of electrons in an exotic human-made element shows that certain properties of heavy elements cannot be predicted using lighter ones.


Spotlight

Tuesday October 03, 2017, 01:05 PM

Stairway to Science

Argonne National Laboratory

Thursday September 28, 2017, 12:05 PM

After-School Energy Rush

Argonne National Laboratory

Thursday September 28, 2017, 10:05 AM

Bringing Diversity Into Computational Science Through Student Outreach

Brookhaven National Laboratory

Thursday September 21, 2017, 03:05 PM

From Science to Finance: SLAC Summer Interns Forge New Paths in STEM

SLAC National Accelerator Laboratory

Thursday September 07, 2017, 02:05 PM

Students Discuss 'Cosmic Opportunities' at 45th Annual SLAC Summer Institute

SLAC National Accelerator Laboratory

Thursday August 31, 2017, 05:05 PM

Binghamton University Opens $70 Million Smart Energy Building

Binghamton University, State University of New York

Wednesday August 23, 2017, 05:05 PM

Widening Horizons for High Schoolers with Code

Argonne National Laboratory

Saturday May 20, 2017, 12:05 PM

Rensselaer Polytechnic Institute Graduates Urged to Embrace Change at 211th Commencement

Rensselaer Polytechnic Institute (RPI)

Monday May 15, 2017, 01:05 PM

ORNL, University of Tennessee Launch New Doctoral Program in Data Science

Oak Ridge National Laboratory

Friday April 07, 2017, 11:05 AM

Champions in Science: Profile of Jonathan Kirzner

Department of Energy, Office of Science

Wednesday April 05, 2017, 12:05 PM

High-Schooler Solves College-Level Security Puzzle From Argonne, Sparks Interest in Career

Argonne National Laboratory

Tuesday March 28, 2017, 12:05 PM

Champions in Science: Profile of Jenica Jacobi

Department of Energy, Office of Science

Friday March 24, 2017, 10:40 AM

Great Neck South High School Wins Regional Science Bowl at Brookhaven Lab

Brookhaven National Laboratory

Wednesday February 15, 2017, 04:05 PM

Middle Schoolers Test Their Knowledge at Science Bowl Competition

Argonne National Laboratory

Friday January 27, 2017, 04:00 PM

Haslam Visits ORNL to Highlight State's Role in Discovering Tennessine

Oak Ridge National Laboratory

Tuesday November 08, 2016, 12:05 PM

Internship Program Helps Foster Development of Future Nuclear Scientists

Oak Ridge National Laboratory

Friday May 13, 2016, 04:05 PM

More Than 12,000 Explore Jefferson Lab During April 30 Open House

Thomas Jefferson National Accelerator Facility

Monday April 25, 2016, 05:05 PM

Giving Back to National Science Bowl

Ames Laboratory

Friday March 25, 2016, 12:05 PM

NMSU Undergrad Tackles 3D Particle Scattering Animations After Receiving JSA Research Assistantship

Thomas Jefferson National Accelerator Facility

Tuesday February 02, 2016, 10:05 AM

Shannon Greco: A Self-Described "STEM Education Zealot"

Princeton Plasma Physics Laboratory

Monday November 16, 2015, 04:05 PM

Rare Earths for Life: An 85th Birthday Visit with Mr. Rare Earth

Ames Laboratory

Tuesday October 20, 2015, 01:05 PM

Meet Robert Palomino: 'Give Everything a Shot!'

Brookhaven National Laboratory

Tuesday April 22, 2014, 11:30 AM

University of Utah Makes Solar Accessible

University of Utah

Wednesday March 06, 2013, 03:40 PM

Student Innovator at Rensselaer Polytechnic Institute Seeks Brighter, Smarter, and More Efficient LEDs

Rensselaer Polytechnic Institute (RPI)

Friday November 16, 2012, 10:00 AM

Texas Tech Energy Commerce Students, Community Light up Tent City

Texas Tech University

Wednesday November 23, 2011, 10:45 AM

Don't Get 'Frosted' Over Heating Your Home This Winter

Temple University

Wednesday July 06, 2011, 06:00 PM

New Research Center To Tackle Critical Challenges Related to Aircraft Design, Wind Energy, Smart Buildings

Rensselaer Polytechnic Institute (RPI)

Friday April 22, 2011, 09:00 AM

First Polymer Solar-Thermal Device Heats Home, Saves Money

Wake Forest University

Friday April 15, 2011, 12:25 PM

Like Superman, American University Will Get Its Energy from the Sun

American University

Thursday February 10, 2011, 05:00 PM

ARRA Grant to Help Fund Seminary Building Green Roof

University of Chicago

Tuesday December 07, 2010, 05:00 PM

UC San Diego Installing 2.8 Megawatt Fuel Cell to Anchor Energy Innovation Park

University of California San Diego

Monday November 01, 2010, 12:50 PM

Rensselaer Smart Lighting Engineering Research Center Announces First Deployment of New Technology on Campus

Rensselaer Polytechnic Institute (RPI)

Friday September 10, 2010, 12:40 PM

Ithaca College Will Host Regional Clean Energy Summit

Ithaca College

Tuesday July 27, 2010, 10:30 AM

Texas Governor Announces $8.4 Million Award to Create Renewable Energy Institute

Texas Tech University

Friday May 07, 2010, 04:20 PM

Creighton University to Offer New Alternative Energy Program

Creighton University

Wednesday May 05, 2010, 09:30 AM

National Engineering Program Seeks Subject Matter Experts in Energy

JETS Junior Engineering Technical Society

Wednesday April 21, 2010, 12:30 PM

Students Using Solar Power To Create Sustainable Solutions for Haiti, Peru

Rensselaer Polytechnic Institute (RPI)

Wednesday March 03, 2010, 07:00 PM

Helping Hydrogen: Student Inventor Tackles Challenge of Hydrogen Storage

Rensselaer Polytechnic Institute (RPI)

Thursday February 04, 2010, 02:00 PM

Turning Exercise into Electricity

Furman University

Thursday November 12, 2009, 12:45 PM

Campus Leaders Showing the Way to a Sustainable, Clean Energy Future

National Wildlife Federation (NWF)

Tuesday November 03, 2009, 04:20 PM

Furman University Receives $2.5 Million DOE Grant for Geothermal Project

Furman University

Thursday September 17, 2009, 02:45 PM

Could Sorghum Become a Significant Alternative Fuel Source?

Salisbury University

Wednesday September 16, 2009, 11:15 AM

Students Navigating the Hudson River With Hydrogen Fuel Cells

Rensselaer Polytechnic Institute (RPI)

Wednesday September 16, 2009, 10:00 AM

College Presidents Flock to D.C., Urge Senate to Pass Clean Energy Bill

National Wildlife Federation (NWF)

Wednesday July 01, 2009, 04:15 PM

Northeastern Announces New Professional Master's in Energy Systems

Northeastern University

Friday October 12, 2007, 09:35 AM

Kansas Rural Schools To Receive Wind Turbines

Kansas State University

Thursday August 17, 2006, 05:30 PM

High Gas Prices Here to Stay, Says Engineering Professor

Rowan University





Showing results

0-4 Of 2215