DOE News
    Doe Science news source
    The DOE Science News Source is a Newswise initiative to promote research news from the Office of Science of the DOE to the public and news media.
    • 2015-02-25 11:00:00
    • Article ID: 630260

    New Flow Battery to Keep Big Cities Lit, Green & Safe

    Smaller, cheaper battery's energy density exceeds other flow batteries

    RICHLAND, Wash. – Ensuring the power grid keeps the lights on in large cities could be easier with a new battery design that packs far more energy than any other battery of its kind and size.

    The new zinc-polyiodide redox flow battery, described in Nature Communications, uses an electrolyte that has more than two times the energy density of the next-best flow battery used to store renewable energy and support the power grid. And its energy density is approaching that of a type of lithium-ion battery used to power portable electronic devices and some small electric vehicles.

    "With improved energy density and inherent fire safety, flow batteries could provide long-duration energy storage for the tight confines of urban settings, where space is at a premium,” said Imre Gyuk, energy storage program manager at the Department of Energy’s Office of Electricity Delivery and Energy Reliability, which funded this research. “This would enhance the resiliency and flexibility of the local electrical grid.”

    “Another, unexpected bonus of this electrolyte’s high energy density is it could potentially expand the use of flow batteries into mobile applications such as powering trains and cars,” said the study’s corresponding author, Wei Wang, a materials scientist at DOE’s Pacific Northwest National Laboratory.

    Going with the flow

    Both flow and lithium-ion batteries were invented in the 1970s, but only the lithium-ion variety took off at that time. Lithium-ion batteries could carry much more energy in a smaller space than flow batteries, making them more versatile. As a result, lithium-ion batteries have been used to power portable electronics for many years. And utilities have begun using them to store the increasing amounts of renewable energy generated at wind farms and solar power facilities.

    But the high-energy lithium-ion batteries’ packaging can make them prone to overheating and catching fire. Flow batteries, on the other hand, store their active chemicals separately until power is needed, greatly reducing safety concerns. This feature has prompted researchers and developers to take a serious second look at flow batteries.

    Stacking up against the competition

    Like other flow batteries, the zinc-polyiodide battery produces power by pumping liquid from external tanks into the battery’s stack, a central area where the liquids are mixed. The external tanks in PNNL’s new battery hold aqueous electrolytes, watery solutions with dissolved chemicals that store energy.

    When the battery is fully discharged, both tanks hold the same electrolyte solution: a mixture of the positively charged zinc ions, Zn2+, and negatively charged iodide ion, I-. But when the battery is charged, one of the tanks also holds another negative ion, polyiodide, I3-. When power is needed, the two liquids are pumped into the central stack. Inside the stack, zinc ions pass through a selective membrane and change into metallic zinc on the stack’s negative side. This process converts energy that’s chemically stored in the electrolyte into electricity that can power buildings and support the power grid’s operations.

    To test the feasibility of their new battery concept, Wei and his PNNL colleagues created a small battery on a lab countertop. They mixed the electrolyte solution, separating a black zinc-polyiodide liquid and a clear zinc-iodide liquid in two glass vials as miniature tanks. Hoses were connected between the vials, a pump and a small stack.

    They put the 12-watt-hour capacity battery – comparable to about two iPhone batteries – through a series of tests, including determining how different concentrations of zinc and iodide in the electrolyte affected energy storage. Electrical capacity is measured in watt-hours; electric cars use about 350 watt-hours to drive one mile in the city.

    More power to it

    The demonstration battery put out far more energy for its size than today’s most commonly used flow batteries: the zinc-bromide battery and the vanadium battery. PNNL’s zinc-polyiodide battery also had an energy output that was about 70 percent that of a common lithium-ion battery called a lithium iron phosphate battery, which is used in portable electronics and in some small electric vehicles.

    Lab tests revealed the demonstration battery discharged 167 watt-hours per liter of electrolyte. In comparison, zinc-bromide flow batteries generate about 70 watt-hours per liter, vanadium flow batteries can create between 15 and 25 watt-hours per liter, and standard lithium iron phosphate batteries could put out about 233 watt-hours per liter.. Theoretically, the team calculated their new battery could discharge even more – up to 322 watt-hours per liter – if more chemicals were dissolved in the electrolyte.

    Safe and versatile, but not perfect yet

    PNNL’s zinc-polyiodide battery is also safer because its electrolyte isn’t acidic like most other flow batteries. It’s nearly impossible for the water-based electrolyte to catch fire and it doesn’t require expensive materials that are needed to withstand the corrosive nature of other flow batteries.

    Another advantage of PNNL’s new flow battery is that it can operate in extreme climates. The electrolyte allows it to work well in temperatures as cold as -4 degrees Fahrenheit and as warm as +122 degrees. Many batteries have much smaller operating windows and can require heating and cooling systems, which cut into a battery’s net power production.

    One problem the team encountered was a build-up of metallic zinc that grew from the central stack’s negative electrode and went through the membrane, making the battery less efficient. Researchers reduced the buildup, called zinc dendrite, by adding alcohol to the electrolyte solution.

    Managing zinc dendrite formation will be a key in enabling PNNL’s zinc-polyiodide battery to be used in the real world. Wei and his colleagues will continue to experiment with different alcohols and other additives and use advanced instruments to characterize how the battery’s materials respond to those additives. The team will also build a larger, 100-watt-hour model of the battery for additional testing.

    Researchers characterized the new battery’s chemical interactions using a variety of advanced instruments – including nuclear magnetic resonance, Raman spectroscopy, mass spectroscopy and more – at EMSL, the Environmental Molecular Sciences Laboratory, a DOE Office of Science national user facility at PNNL. This research was funded by the Department of Energy’s Office of Electricity Delivery and Energy Reliability.

    # # #

    REFERENCE: Bin Li, Zimin Nie, M. Vijayakumar, Guosheng Li, Jun Liu, Vincent Sprenkle, Wei Wang, “Ambipolar Zinc-Polyiodide Electrolyte for High Energy Density Aqueous Redox Flow Battery,” Nature Communications, Feb. 24, 2015, doi:10.1038/ncomms7303, http://www.nature.com/ncomms/2015/150224/ncomms7303/full/ncomms7303.html

    Interdisciplinary teams at Pacific Northwest National Laboratory address many of America's most pressing issues in energy, the environment and national security through advances in basic and applied science. Founded in 1965, PNNL employs 4,300 staff and has an annual budget of more than $1 billion. It is managed by Battelle for the U.S. Department of Energy's Office of Science. As the single largest supporter of basic research in the physical sciences in the United States, the Office of Science is working to address some of the most pressing challenges of our time. For more information on PNNL, visit the PNNL News Center, or follow PNNL on Facebook, Google+, LinkedIn and Twitter.

    EMSL, the Environmental Molecular Sciences Laboratory, is a national scientific user facility sponsored by the Department of Energy's Office of Science. Located at Pacific Northwest National Laboratory in Richland, Wash., EMSL offers an open, collaborative environment for scientific discovery to researchers around the world. Its integrated computational and experimental resources enable researchers to realize important scientific insights and create new technologies. Follow EMSL on Facebook, LinkedIn and Twitter.

    X
    X
    X
    • Filters

    • × Clear Filters

    Stronger, lighter, greener

    A new award-winning magnet technology invented at the U.S. Department of Energy's Argonne National Laboratory could help drive the nation's transition from gas-powered vehicles to electric and hybrid power more rapidly, at lower cost, and in a more environmentally friendly way.

    Science Up-Close: Developing a Cookbook for Efficient Fusion Energy

    To develop a future fusion reactor, scientists need to understand how and why plasma in fusion experiments moves into a "high-confinement mode" where particles and heat can't escape. Scientists at the Department of Energy's Princeton Plasma Physics Laboratory simulated the transition into that mode starting from the most basic physics principles.

    Peering into the Mist: How Water Vapor Changes Metal at the Atomic Level

    New insights into molecular-level processes could help prevent corrosion and improve catalytic conversion.

    Neutron science publications reach new highs at ORNL's flagship facilities

    The High Flux Isotope Reactor and the Spallation Neutron Source at the Department of Energy's Oak Ridge National Laboratory have reached new levels of increased science productivity. In 2018, a record high of more than 500 scientific instrument publications were produced between HFIR and SNS--based on neutron beamline experiments conducted by more than 1,200 US and international researchers who used the world-leading facilities.

    Fiery sighting: A new physics of eruptions that damage fusion experiments

    Feature describes first direct sighting of a trigger for bursts of heat that can disrupt fusion reactions.

    Microbial Types May Prove Key to Gas Releases from Thawing Permafrost

    Scientists discover key types of microbes that degrade organic matter and release carbon dioxide and methane into the atmosphere.

    An effect that Einstein helped discover 100 years ago offers new insight into a puzzling magnetic phenomenon

    Experiments at the Department of Energy's SLAC National Accelerator Laboratory have seen for the first time what happens when magnetic materials are demagnetized at ultrafast speeds of millionths of a billionth of a second: The atoms on the surface of the material move, much like the iron bar did. The work, done at SLAC's Linac Coherent Light Source (LCLS) X-ray laser, was published in Nature earlier this month.

    Found: A precise method for determining how waves and particles affect fusion reactions

    Like surfers catching ocean waves, particles within plasma can ride waves oscillating through the plasma during fusion energy experiments. Now a team of physicists led by PPPL has devised a faster method to determine how much this interaction contributes to efficiency loss in tokamaks.

    Discovery adapts natural membrane to make hydrogen fuel from water

    In a recent study from the U.S. Department of Energy's (DOE) Argonne National Laboratory, scientists have combined two membrane-bound protein complexes to perform a complete conversion of water molecules to hydrogen and oxygen.

    How Plants Regulate Sugar Deposition in Cell Walls

    Identified genes involved in plant cell wall polysaccharide production and restructuring could aid in engineering bioenergy crops.


    • Filters

    • × Clear Filters

    Top 10 Discoveries of 2018

    Every year, the U.S. Department of Energy's (DOE) Brookhaven National Laboratory compiles a list of the biggest advances made by the Lab's staff scientists, engineers, and visiting researchers. From uncovering mysteries of the universe to building better batteries, here, in no particular order, are our picks for the top 10 discoveries of 2018.

    U.S. Department of Energy Announces $33 Million for Small Business Research and Development Grants

    The U.S. Department of Energy announced it will award 189 grants totaling $33 million to 149 small businesses in 32 states.

    DOE to Provide $16 Million for New Research into Atmospheric and Terrestrial Processes

    The U.S. Department of Energy (DOE) announced a plan to provide $16 million for new observational research aimed at improving the accuracy of today's climate and earth system models.

    Machine learning award powers Argonne leadership in engine design

    When attempting to design engines to be more fuel-efficient and emissions-free, automotive manufacturers have to take into account all the complexity inherent in the combustion process.

    ORNL partners with industry to address multiple nuclear technology challenges

    The Department of Energy's Oak Ridge National Laboratory is collaborating with industry on six new projects focused on advancing commercial nuclear energy technologies that offer potential improvements to current nuclear reactors and move new reactor designs closer to deployment.

    Lithium earns honors for three physicists working to bring the energy that powers the sun to Earth

    Feature describes research of three PPPL physicists who have won the laboratory's 2018 outstanding research awards

    DOE approves technical plan and cost estimate to upgrade Argonne facility; Project will create X-rays that illuminate the atomic scale, in 3D

    The U.S. Department of Energy has approved the technical scope, cost estimate and plan of work for an upgrade of the Advanced Photon Source, a major storage-ring X-ray source at Argonne.

    Costas Soukoulis elected to National Academy of Inventors

    Costas Soukoulis, Ames Laboratory senior scientist and Iowa State University Frances M. Craig Endowed Chair and Distinguished Professor, has been named as a 2018 National Academy of Inventors (NAI) Fellow.

    Biophysicist F. William Studier Elected Fellow of the National Academy of Inventors

    F. William Studier, a Senior Biophysicist Emeritus at the U.S. Department of Energy's Brookhaven National Laboratory and Adjunct Professor of Biochemistry at Stony Brook University, has been elected as a Fellow of the National Academy of Inventors (NAI). He is among 148 renowned academic inventors being recognized by NAI for 2018.

    Blast to the future

    A grant from DOE's Technology Commercialization Fund will help researchers at Argonne and industry partners seek improvements to U.S. manufacturing by making discovery and design of new materials more efficient.


    • Filters

    • × Clear Filters

    Rapid Lake Draining on Ice Sheets Changes How Water Moves in Unexpected Ways

    Widespread fracturing during lake drainage triggers vertical shafts to form that affect the Greenland Ice Sheet.

    New Historical Emissions Trends Estimated with the Community Emissions Data System

    The data system will allow for more detailed, consistent, and up-to-date global emissions trends that will aid in understanding aerosol effects.

    Peering into the Mist: How Water Vapor Changes Metal at the Atomic Level

    New insights into molecular-level processes could help prevent corrosion and improve catalytic conversion.

    Microbial Types May Prove Key to Gas Releases from Thawing Permafrost

    Scientists discover key types of microbes that degrade organic matter and release carbon dioxide and methane into the atmosphere.

    New Method Knocks Out Yeast Genes with Single-Point Precision

    Researchers can precisely study how different genes affect key properties in a yeast used industrially to produce fuel and chemicals.

    How Plants Regulate Sugar Deposition in Cell Walls

    Identified genes involved in plant cell wall polysaccharide production and restructuring could aid in engineering bioenergy crops.

    Scientists Identify Gene Cluster in Budding Yeasts with Major Implications for Renewable Energy

    How yeast partition carbon into a metabolite may offer insights into boosting production for biofuels.

    More Designer Peptides, More Possibilities

    A combined experimental and modeling approach contributes to understanding small proteins with potential use in industrial, therapeutic applications.

    Deep Learning for Electron Microscopy

    Artificial intelligence on Summit to discover atomic-scale structures.

    Clarifying Rates of Methylmercury Production

    New model provides more accurate estimates of how fast microbes produce a mercury-based neurotoxin.


    Spotlight

    Friday January 18, 2019, 05:05 PM

    Chemistry intern inspired by Argonne's real-world science

    Argonne National Laboratory

    Friday January 18, 2019, 04:05 PM

    Chasing a supernova

    Argonne National Laboratory

    Tuesday January 08, 2019, 02:05 PM

    Argonne intern streamlines the beamline

    Argonne National Laboratory

    Thursday October 11, 2018, 04:00 PM

    Research on Light-Matter Interaction Could Lead to Improved Electronic and Optoelectronic Devices

    Rensselaer Polytechnic Institute (RPI)

    Wednesday October 03, 2018, 07:05 PM

    Innovating Our Energy Future

    Oregon State University, College of Engineering

    Tuesday October 02, 2018, 03:05 PM

    Physics graduate student takes her thesis research to a Department of Energy national lab

    University of Alabama at Birmingham

    Friday September 21, 2018, 01:05 PM

    "Model" students enjoy Argonne campus life

    Argonne National Laboratory

    Thursday September 06, 2018, 01:05 PM

    Writing Code for a More Skilled and Diverse STEM Workforce

    Brookhaven National Laboratory

    Tuesday September 04, 2018, 11:30 AM

    New graduate student summer school launches at Princeton Plasma Physics Laboratory

    Princeton Plasma Physics Laboratory

    Friday August 31, 2018, 06:05 PM

    The Gridlock State

    California State University (CSU) Chancellor's Office

    Friday August 31, 2018, 02:05 PM

    Meet Jasmine Hatcher and Trishelle Copeland-Johnson

    Brookhaven National Laboratory

    Friday August 24, 2018, 11:05 AM

    Argonne hosts Modeling, Experimentation and Validation Summer School

    Argonne National Laboratory

    Wednesday August 22, 2018, 01:05 PM

    Students affected by Hurricane Maria bring their research to SLAC

    SLAC National Accelerator Laboratory

    Wednesday August 22, 2018, 10:05 AM

    Brookhaven Lab Pays Tribute to 2018 Summer Interns

    Brookhaven National Laboratory

    Monday August 20, 2018, 12:05 PM

    Changing How Buildings Are Made

    Washington University in St. Louis

    Thursday August 16, 2018, 12:05 PM

    CSUMB Selected to Host Architecture at Zero Competition in 2019

    California State University, Monterey Bay

    Friday July 20, 2018, 03:00 PM

    Department of Energy Invests $64 Million in Advanced Nuclear Technology

    Rensselaer Polytechnic Institute (RPI)

    Thursday July 19, 2018, 05:00 PM

    Professor Miao Yu Named the Priti and Mukesh Chatter '82 Career Development Professor

    Rensselaer Polytechnic Institute (RPI)

    Tuesday July 03, 2018, 11:05 AM

    2018 RHIC & AGS Annual Users' Meeting: 'Illuminating the QCD Landscape'

    Brookhaven National Laboratory

    Friday June 29, 2018, 06:05 PM

    Argonne welcomes The Martian author Andy Weir

    Argonne National Laboratory

    Monday June 18, 2018, 09:55 AM

    Creating STEM Knowledge and Innovations to Solve Global Issues Like Water, Food, and Energy

    Illinois Mathematics and Science Academy (IMSA)

    Friday June 15, 2018, 10:00 AM

    Professor Emily Liu Receives $1.8 Million DoE Award for Solar Power Systems Research

    Rensselaer Polytechnic Institute (RPI)

    Thursday June 07, 2018, 03:05 PM

    Celebrating 40 years of empowerment in science

    Argonne National Laboratory

    Monday May 07, 2018, 10:30 AM

    Introducing Graduate Students Across the Globe to Photon Science

    Brookhaven National Laboratory

    Wednesday May 02, 2018, 04:05 PM

    Students from Massachusetts and Washington Win DOE's 28th National Science Bowl(r)

    Department of Energy, Office of Science

    Thursday April 12, 2018, 07:05 PM

    The Race for Young Scientific Minds

    Argonne National Laboratory

    Wednesday March 14, 2018, 02:05 PM

    Q&A: Al Ashley Reflects on His Efforts to Diversify SLAC and Beyond

    SLAC National Accelerator Laboratory

    Thursday February 15, 2018, 12:05 PM

    Insights on Innovation in Energy, Humanitarian Aid Highlight UVA Darden's Net Impact Week

    University of Virginia Darden School of Business

    Friday February 09, 2018, 11:05 AM

    Ivy League Graduate, Writer and Activist with Dyslexia Visits CSUCI to Reframe the Concept of Learning Disabilities

    California State University, Channel Islands

    Wednesday January 17, 2018, 12:05 PM

    Photographer Adam Nadel Selected as Fermilab's New Artist-in-Residence for 2018

    Fermi National Accelerator Laboratory (Fermilab)

    Wednesday January 17, 2018, 12:05 PM

    Fermilab Computing Partners with Argonne, Local Schools for Hour of Code

    Fermi National Accelerator Laboratory (Fermilab)

    Wednesday December 20, 2017, 01:05 PM

    Q&A: Sam Webb Teaches X-Ray Science from a Remote Classroom

    SLAC National Accelerator Laboratory

    Monday December 18, 2017, 01:05 PM

    The Future of Today's Electric Power Systems

    Rensselaer Polytechnic Institute (RPI)

    Monday December 18, 2017, 12:05 PM

    Supporting the Development of Offshore Wind Power Plants

    Rensselaer Polytechnic Institute (RPI)

    Tuesday October 03, 2017, 01:05 PM

    Stairway to Science

    Argonne National Laboratory

    Thursday September 28, 2017, 12:05 PM

    After-School Energy Rush

    Argonne National Laboratory

    Thursday September 28, 2017, 10:05 AM

    Bringing Diversity Into Computational Science Through Student Outreach

    Brookhaven National Laboratory

    Thursday September 21, 2017, 03:05 PM

    From Science to Finance: SLAC Summer Interns Forge New Paths in STEM

    SLAC National Accelerator Laboratory

    Thursday September 07, 2017, 02:05 PM

    Students Discuss 'Cosmic Opportunities' at 45th Annual SLAC Summer Institute

    SLAC National Accelerator Laboratory

    Thursday August 31, 2017, 05:05 PM

    Binghamton University Opens $70 Million Smart Energy Building

    Binghamton University, State University of New York

    Wednesday August 23, 2017, 05:05 PM

    Widening Horizons for High Schoolers with Code

    Argonne National Laboratory

    Saturday May 20, 2017, 12:05 PM

    Rensselaer Polytechnic Institute Graduates Urged to Embrace Change at 211th Commencement

    Rensselaer Polytechnic Institute (RPI)

    Monday May 15, 2017, 01:05 PM

    ORNL, University of Tennessee Launch New Doctoral Program in Data Science

    Oak Ridge National Laboratory

    Friday April 07, 2017, 11:05 AM

    Champions in Science: Profile of Jonathan Kirzner

    Department of Energy, Office of Science

    Wednesday April 05, 2017, 12:05 PM

    High-Schooler Solves College-Level Security Puzzle From Argonne, Sparks Interest in Career

    Argonne National Laboratory





    Showing results

    0-4 Of 2215