Doe Science news source
The DOE Science News Source is a Newswise initiative to promote research news from the Office of Science of the DOE to the public and news media.
  • 2018-01-25 03:00:35
  • Article ID: 688459

Recycling and Reusing Worn Cathodes to Make New Lithium Ion Batteries

  • Credit: David Baillot/UC San Diego Jacobs School of Engineering

    Used cathode particles from spent lithium ion batteries are recycled and regenerated to work as good as new

  • Credit: David Baillot/UC San Diego Jacobs School of Engineering

    (L-R): First author Yang Shi and Professor Zheng Chen of UC San Diego developed a method to recycle and regenerate cathodes of spent lithium ion batteries

Nanoengineers at the University of California San Diego have developed an energy-efficient recycling process that restores used cathodes from spent lithium ion batteries and makes them work just as good as new. The process involves harvesting the degraded cathode particles from a used battery and then boiling and heat treating them. Researchers built new batteries using the regenerated cathodes. Charge storage capacity, charging time and battery lifetime were all restored to their original levels.

This work presents a solution to an environmental concern regarding lithium ion batteries: what to do with them when they wear out. Less than five percent of used lithium ion batteries are recycled today.

“Think about the millions of tons of lithium ion battery waste in the future, especially with the rise of electric vehicles, and the depletion of precious resources like lithium and cobalt—mining more of these resources will contaminate our water and soil. If we can sustainably harvest and reuse materials from old batteries, we can potentially prevent such significant environmental damage and waste,” said Zheng Chen, a professor of nanoengineering at UC San Diego.

Chen, who is affiliated with the Sustainable Power and Energy Center at UC San Diego, says this work could also address economic issues related to battery waste. “The price of lithium, cobalt and nickel has increased significantly. Recovering these expensive materials could lower battery costs,” he said.

The new recycling method, published recently in Green Chemistry, can be used to recover and restore a lithium ion battery cathode material called lithium cobalt oxide, which is widely used in consumer electronic devices including smartphones and laptops. The method also works on NMC, a popular lithium cathode containing nickel, manganese and cobalt, which is used in most electric vehicles.

The method involves first collecting cathode particles from spent lithium ion batteries. Researchers then pressurize the cathode particles in a hot, alkaline, solution containing lithium salt—this solution can be recycled and reused to process more batches. Afterwards, the particles go through a short annealing process in which they are heated to 800 C and then cooled very slowly.

Researchers made new cathodes from the regenerated particles and then tested them in batteries built in the lab. The new cathodes showed the same energy storage capacity, charging time and lifetime as the originals.

An interesting thing about this process, Chen noted, is that it’s essentially the same one that’s used to make the original cathode particles. “We can simply restore the degraded material by putting it through the same processing steps,” he said.

As a lithium ion battery wears out, the cathode material loses some of its lithium atoms. The cathode’s atomic structure also changes such that it’s less capable of moving ions in and out. The recycling process that Chen’s group developed restores both the cathode’s lithium concentration and atomic structure back to their original states.

Overall, the recycling process uses 5.9 megajoules of energy, equivalent to the energy in about three quarters of a cup of gasoline, to restore one kilogram of cathode material. Several other lithium ion battery cathode recycling processes that are being developed use at least twice that energy.

The goal is to optimize this process for industrial scales. Chen’s team is planning to work with battery companies in Asia. A particular area of improvement is the cathode harvesting step, Chen said. Right now, the particles have to be manually picked out from the rest of the battery. Researchers are working on simplifying this step so that the entire process is industrially viable.

Chen’s team is refining this process so that it can be used to recycle any type of lithium ion battery cathode material, in addition to lithium cobalt oxide and lithium NMC. “The goal is to make this a general recycling process for all cathodes,” Chen said. The team is also working on a process to recycle used anodes.

###

The team has filed a provisional patent on this work. Contact Victoria Cajipe in the campus Innovation and Commercialization Office at vcajipe@usd.edu or (858) 822-2304 for licensing information.

Paper title: “Effective regeneration of LiCoO2 from spent lithium-ion batteries: a direct approach towards high-performance active particles.” Authors of the study are Yang Shi and Zheng Chen of UC San Diego and Gen Chen of the University of California Los Angeles.

This work was supported in part by start-up funds from UC San Diego.

X
X
X
  • Filters

  • × Clear Filters

Enhanced Detection of Nuclear Events, Thanks to Deep Learning

Scientists at Pacific Northwest National Laboratory are exploring deep learning to interpret data related to national security, the environment, the cosmos, and breast cancer. In one project a deep neural network is interpreting data about nuclear events as well as - sometimes better than - today's best automated methods or human experts.

A Bit of Quantum Logic--What Did the Atom Say to the Quantum Dot?

Let's talk! Scientists demonstrate coherent coupling between a quantum dot and a donor atom in silicon, vital for moving information inside quantum computers.

Sodium- and Potassium-based Batteries Hold Promise for Cheap Energy Storage

Researchers at the Georgia Institute of Technology have found new evidence suggesting that batteries based on sodium and potassium hold promise as a potential alternative to lithium-based batteries.

ORNL researchers use AI to improve mammogram interpretation

In an effort to reduce errors in the analyses of diagnostic images by health professionals, a team of researchers from Oak Ridge National Laboratory has improved understanding of the cognitive processes involved in image interpretation, work that has enormous potential to improve health outcomes for the hundreds of thousands of American women affected by breast cancer each year. The ORNL-led team found that analyses of mammograms by radiologists were significantly influenced by context bias, or the radiologist's previous diagnostic experiences.

Scientists Make the First Molecular Movie of One of Nature's Most Widely Used Light Sensors

Scientists have made the first molecular movie of the instant when light hits a sensor that's widely used in nature for probing the environment and harvesting energy from light. The sensor, a form of vitamin A known as retinal, is central to a number of important light-driven processes in people, animals, microbes and algae, including human vision and some forms of photosynthesis, and the movie shows it changing shape in a trillionth of an eye blink.

Scientists isolate protein data from the tiniest of caches - single human cells

Scientists have captured the most information yet about proteins within a single human cell, giving scientists one of their clearest looks yet at the molecular happenings inside a human cell. The team detected on average more than 650 proteins in each cell - many times more than conventional techniques capture from single cells.

Researchers Generate Electricity and Hydrogen from Live Bacteria

Using a family of photosynthetic bacteria that commonly live in lakes and seas, researchers at the Technion have developed a technology to generate electricity and hydrogen energy. The researchers believe their technology can serve as a promising source of clean, environment-friendly energy that will not emit pollutants during production or use (hydrogen fuel).

Carbon Nanotube Optics Poised to Provide Pathway to Optical-Based Quantum Cryptography and Quantum Computing

Researchers at Los Alamos and partners in France and Germany are exploring the enhanced potential of carbon nanotubes as single-photon emitters for quantum information processing. Their analysis of progress in the field is published in this week's edition of the journal Nature Materials.

New Tech Uses Isomeric Beams to Study How and Where the Galaxy Makes One of Its Most Common Elements

A new measurement using a beam of aluminum-26 prepared in a metastable state allows researchers to better understand the creation of the elements in our galaxy.

Scientists Use Neutrons to Take a Deeper Look at Record Boost in Thermoelectric Efficiency

Neutron facilities at Oak Ridge National Laboratory are aiding scientists in research to boost the power and efficiency of thermoelectric materials. These performance increases could enable more cost-effective and practical uses for thermoelectrics, with wider industry adoption, to improve fuel economy in vehicles, make power plants more efficient, and advance body heat-powered technologies for watches and smartphones.


  • Filters

  • × Clear Filters

´╗┐Stony Brook's AERTC Selected for Leadership Role in Nationwide Consortium on Offshore Wind Industry

Stony Brook's Advanced Energy Research and Technology Center (AERTC) will play a key role in a nationwide research and development consortium for the offshore wind industry. The New York State Energy Research and Development Authority was awarded a $18.5 million U.S. Department of Energy grant to establish the National Offshore Wind Research and Development Consortium, Governor Andrew M. Cuomo announced last week. New York State, through NYSERDA, has committed an additional $20.5 million to fund the consortium supporting Gov. Cuomo's initiative Reforming the Energy Vision (REV).

Professor Emily Liu Receives $1.8 Million DoE Award for Solar Power Systems Research

Li (Emily) Liu, associate professor of nuclear engineering and engineering physics in the Department of Mechanical, Aerospace, and Nuclear Engineering at Rensselaer Polytechnic Institute, has been selected by the U.S. Department of Energy Solar Energy Technologies Office (SETO) to receive a $1.8 million award to study high-temperature molten-salt properties and corrosion mechanisms.

Vasilis Fthenakis Receives IEEE's William R. Cherry Award

UPTON, NY; Vasilis Fthenakis, a Senior Scientist Emeritus at the U.S. Department of Energy's (DOE) Brookhaven National Laboratory and Founder and Director of the Center for Life Cycle Analysis at Columbia University, will receive the 2018 William R. Cherry Award from the Institute of Electrical & Electronics Engineers (IEEE).

New PPPL director Steve Cowley is honored with knighthood by Queen Elizabeth II

Steven Cowley, newly named director of the U.S. Department of Energy's (DOE) Princeton Plasma Physics Laboratory (PPPL) effective July 1, has received a knighthood from Queen Elizabeth "for services to science and the development of nuclear fusion."

UVA Darden Releases Policy Playbook Identifying Six Actions to Catalyze Clean-Tech Innovation

Moving the needle on climate change will require substantive and disruptive innovation across multiple industry sectors. Public and private investment focused on a few key areas could have a significant impact, according to a new policy playbook released by the Batten Institute for Entrepreneurship and Innovation on 8 June.

Work Begins on New SLAC Facility for Revolutionary Accelerator Science

The Department of Energy's SLAC National Accelerator Laboratory has started to assemble a new facility for revolutionary accelerator technologies that could make future accelerators 100 to 1,000 times smaller and boost their capabilities.

Oak Ridge National Laboratory Launches America's New Top Supercomputer for Science

The U.S. Department of Energy's Oak Ridge National Laboratory unveiled Summit as the world's most powerful and smartest scientific supercomputer.

Takeuchi Receives European Inventor Award 2018 in the Non-EPO Countries Category

Prolific patent-holder won for inventing battery that increases the lifespan of implantable defibrillators fivefold, greatly reducing need for reoccurring surgery

Steve Kevan Named Next Director of Berkeley Lab's Advanced Light Source

After an international search, Stephen D. "Steve" Kevan has been named the new director of the Advanced Light Source (ALS) at the U.S. Department of Energy's Lawrence Berkeley National Laboratory.

International corrosion society elects first Sandia fellow

Sandia National Laboratories materials scientist David Enos has been elected a fellow of NACE International, the chief professional society for corrosion engineering. He is the first Sandia employee to receive the honor.


  • Filters

  • × Clear Filters

A Bit of Quantum Logic--What Did the Atom Say to the Quantum Dot?

Let's talk! Scientists demonstrate coherent coupling between a quantum dot and a donor atom in silicon, vital for moving information inside quantum computers.

New Tech Uses Isomeric Beams to Study How and Where the Galaxy Makes One of Its Most Common Elements

A new measurement using a beam of aluminum-26 prepared in a metastable state allows researchers to better understand the creation of the elements in our galaxy.

Simulations of Magnetically Confined Plasmas Reveal a Self-Regulating Stabilizing Mechanism

A mysterious mechanism that prevents instabilities may be similar to the process that maintains the Earth's magnetic field.

Seeing All the Colors of the Plasma Wind

2-D velocity imaging helps fusion researchers understand the role of ion winds (aka flows) in the boundary of tokamak plasmas.

Renewable Solvents Derived From Lignin Lowers Waste in Biofuel Production

New class of solvents breaks down plant biomass into sugars for biofuels and bioproducts in a closed-loop biorefinery concept.

Scientists Studying Nuclear Spin Make a Surprising Discovery

The size of a nucleus appears to influence the direction of certain particles emitted from collisions with spinning protons.

Simulating Turbulent Bubbly Flows in Nuclear Reactors

With a better understanding of bubbly flows, researchers can improve the safety and operation of our nuclear reactors.

Solving a Magnesium Mystery in Rechargeable Battery Performance

Study reveals surprising, bad chemical reactivity in battery components previously considered compatible.

Changing the Surroundings Improves Catalysis

Water changes how cobalt-based molecule turns carbon dioxide into chemical feedstock.

How to Draw a Line Narrower Than a Cold Virus

Scientists use ion beams to write high-purity metal structures, enabling nanofabrication opportunities.


Spotlight

Monday June 18, 2018, 09:55 AM

Creating STEM Knowledge and Innovations to Solve Global Issues Like Water, Food, and Energy

Illinois Mathematics and Science Academy (IMSA)

Friday June 15, 2018, 10:00 AM

Professor Emily Liu Receives $1.8 Million DoE Award for Solar Power Systems Research

Rensselaer Polytechnic Institute (RPI)

Thursday June 07, 2018, 03:05 PM

Celebrating 40 years of empowerment in science

Argonne National Laboratory

Monday May 07, 2018, 10:30 AM

Introducing Graduate Students Across the Globe to Photon Science

Brookhaven National Laboratory

Wednesday May 02, 2018, 04:05 PM

Students from Massachusetts and Washington Win DOE's 28th National Science Bowl(r)

Department of Energy, Office of Science

Thursday April 12, 2018, 07:05 PM

The Race for Young Scientific Minds

Argonne National Laboratory

Wednesday March 14, 2018, 02:05 PM

Q&A: Al Ashley Reflects on His Efforts to Diversify SLAC and Beyond

SLAC National Accelerator Laboratory

Thursday February 15, 2018, 12:05 PM

Insights on Innovation in Energy, Humanitarian Aid Highlight UVA Darden's Net Impact Week

University of Virginia Darden School of Business

Friday February 09, 2018, 11:05 AM

Ivy League Graduate, Writer and Activist with Dyslexia Visits CSUCI to Reframe the Concept of Learning Disabilities

California State University, Channel Islands

Wednesday January 17, 2018, 12:05 PM

Photographer Adam Nadel Selected as Fermilab's New Artist-in-Residence for 2018

Fermi National Accelerator Laboratory (Fermilab)

Wednesday January 17, 2018, 12:05 PM

Fermilab Computing Partners with Argonne, Local Schools for Hour of Code

Fermi National Accelerator Laboratory (Fermilab)

Wednesday December 20, 2017, 01:05 PM

Q&A: Sam Webb Teaches X-Ray Science from a Remote Classroom

SLAC National Accelerator Laboratory

Monday December 18, 2017, 01:05 PM

The Future of Today's Electric Power Systems

Rensselaer Polytechnic Institute (RPI)

Monday December 18, 2017, 12:05 PM

Supporting the Development of Offshore Wind Power Plants

Rensselaer Polytechnic Institute (RPI)

Tuesday October 03, 2017, 01:05 PM

Stairway to Science

Argonne National Laboratory

Thursday September 28, 2017, 12:05 PM

After-School Energy Rush

Argonne National Laboratory

Thursday September 28, 2017, 10:05 AM

Bringing Diversity Into Computational Science Through Student Outreach

Brookhaven National Laboratory

Thursday September 21, 2017, 03:05 PM

From Science to Finance: SLAC Summer Interns Forge New Paths in STEM

SLAC National Accelerator Laboratory

Thursday September 07, 2017, 02:05 PM

Students Discuss 'Cosmic Opportunities' at 45th Annual SLAC Summer Institute

SLAC National Accelerator Laboratory

Thursday August 31, 2017, 05:05 PM

Binghamton University Opens $70 Million Smart Energy Building

Binghamton University, State University of New York

Wednesday August 23, 2017, 05:05 PM

Widening Horizons for High Schoolers with Code

Argonne National Laboratory

Saturday May 20, 2017, 12:05 PM

Rensselaer Polytechnic Institute Graduates Urged to Embrace Change at 211th Commencement

Rensselaer Polytechnic Institute (RPI)

Monday May 15, 2017, 01:05 PM

ORNL, University of Tennessee Launch New Doctoral Program in Data Science

Oak Ridge National Laboratory

Friday April 07, 2017, 11:05 AM

Champions in Science: Profile of Jonathan Kirzner

Department of Energy, Office of Science

Wednesday April 05, 2017, 12:05 PM

High-Schooler Solves College-Level Security Puzzle From Argonne, Sparks Interest in Career

Argonne National Laboratory

Tuesday March 28, 2017, 12:05 PM

Champions in Science: Profile of Jenica Jacobi

Department of Energy, Office of Science

Friday March 24, 2017, 10:40 AM

Great Neck South High School Wins Regional Science Bowl at Brookhaven Lab

Brookhaven National Laboratory

Wednesday February 15, 2017, 04:05 PM

Middle Schoolers Test Their Knowledge at Science Bowl Competition

Argonne National Laboratory

Friday January 27, 2017, 04:00 PM

Haslam Visits ORNL to Highlight State's Role in Discovering Tennessine

Oak Ridge National Laboratory

Tuesday November 08, 2016, 12:05 PM

Internship Program Helps Foster Development of Future Nuclear Scientists

Oak Ridge National Laboratory

Friday May 13, 2016, 04:05 PM

More Than 12,000 Explore Jefferson Lab During April 30 Open House

Thomas Jefferson National Accelerator Facility

Monday April 25, 2016, 05:05 PM

Giving Back to National Science Bowl

Ames Laboratory

Friday March 25, 2016, 12:05 PM

NMSU Undergrad Tackles 3D Particle Scattering Animations After Receiving JSA Research Assistantship

Thomas Jefferson National Accelerator Facility

Tuesday February 02, 2016, 10:05 AM

Shannon Greco: A Self-Described "STEM Education Zealot"

Princeton Plasma Physics Laboratory

Monday November 16, 2015, 04:05 PM

Rare Earths for Life: An 85th Birthday Visit with Mr. Rare Earth

Ames Laboratory

Tuesday October 20, 2015, 01:05 PM

Meet Robert Palomino: 'Give Everything a Shot!'

Brookhaven National Laboratory

Tuesday April 22, 2014, 11:30 AM

University of Utah Makes Solar Accessible

University of Utah

Wednesday March 06, 2013, 03:40 PM

Student Innovator at Rensselaer Polytechnic Institute Seeks Brighter, Smarter, and More Efficient LEDs

Rensselaer Polytechnic Institute (RPI)

Friday November 16, 2012, 10:00 AM

Texas Tech Energy Commerce Students, Community Light up Tent City

Texas Tech University

Wednesday November 23, 2011, 10:45 AM

Don't Get 'Frosted' Over Heating Your Home This Winter

Temple University

Wednesday July 06, 2011, 06:00 PM

New Research Center To Tackle Critical Challenges Related to Aircraft Design, Wind Energy, Smart Buildings

Rensselaer Polytechnic Institute (RPI)

Friday April 22, 2011, 09:00 AM

First Polymer Solar-Thermal Device Heats Home, Saves Money

Wake Forest University

Friday April 15, 2011, 12:25 PM

Like Superman, American University Will Get Its Energy from the Sun

American University

Thursday February 10, 2011, 05:00 PM

ARRA Grant to Help Fund Seminary Building Green Roof

University of Chicago

Tuesday December 07, 2010, 05:00 PM

UC San Diego Installing 2.8 Megawatt Fuel Cell to Anchor Energy Innovation Park

University of California San Diego

Monday November 01, 2010, 12:50 PM

Rensselaer Smart Lighting Engineering Research Center Announces First Deployment of New Technology on Campus

Rensselaer Polytechnic Institute (RPI)

Friday September 10, 2010, 12:40 PM

Ithaca College Will Host Regional Clean Energy Summit

Ithaca College

Tuesday July 27, 2010, 10:30 AM

Texas Governor Announces $8.4 Million Award to Create Renewable Energy Institute

Texas Tech University





Showing results

0-4 Of 2215