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Chemists ID Catalytic 'Key' for Converting CO2 to Methanol

Results from experiments and computational modeling studies that definitively identify the "active site" of a catalyst commonly used for making methanol from CO2 will guide the design of improved catalysts for transforming this pollutant to useful chemicals.

Cryo-Electron Microscopy Achieves Unprecedented Resolution Using New Computational Methods

Cryo-electron microscopy (cryo-EM)--which enables the visualization of viruses, proteins, and other biological structures at the molecular level--is a critical tool used to advance biochemical knowledge. Now Berkeley Lab researchers have extended cryo-EM's impact further by developing a new computational algorithm instrumental in constructing a 3-D atomic-scale model of bacteriophage P22 for the first time.

New Study Maps Space Dust in 3-D

A new Berkeley Lab-led study provides detailed 3-D views of space dust in the Milky Way, which could help us understand the properties of this dust and how it affects views of distant objects.

Single-Angle Ptychography Allows 3D Imaging of Stressed Materials

Scientists have used a new X-ray diffraction technique called Bragg single-angle ptychography to get a clear picture of how planes of atoms shift and squeeze under stress.

New Feedback System Could Allow Greater Control Over Fusion Plasma

A physicist has created a new system that will let scientists control the energy and rotation of plasma in real time in a doughnut-shaped machine known as a tokamak.

Towards Super-Efficient, Ultra-Thin Silicon Solar Cells

Researchers from Ames Laboratory used supercomputers at NERSC to evaluate a novel approach for creating more energy-efficient ultra-thin crystalline silicon solar cells by optimizing nanophotonic light trapping.

Study IDs Link Between Sugar Signaling and Regulation of Oil Production in Plants

UPTON, NY--Even plants have to live on an energy budget. While they're known for converting solar energy into chemical energy in the form of sugars, plants have sophisticated biochemical mechanisms for regulating how they spend that energy. Making oils costs a lot. By exploring the details of this delicate energy balance, a group of scientists from the U.

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A new technique synchronized high-energy electrons with an ultrafast laser pulse to probe how vibrational states of atoms change in time.

Rare Earth Recycling

A new energy-efficient separation of rare earth elements could provide a new domestic source of critical materials.

Two-Dimensional MXene Materials Get Their Close-Up

Researchers have long sought electrically conductive materials for economical energy-storage devices. Two-dimensional (2D) ceramics called MXenes are contenders.


Three SLAC Employees Awarded Lab's Highest Honor

At a March 7 ceremony, three employees of the Department of Energy's SLAC National Accelerator Laboratory were awarded the lab's highest honor ­- the SLAC Director's Award.

Dan Sinars Represents Sandia in First Energy Leadership Class

Dan Sinars, a senior manager in Sandia National Laboratories' pulsed power center, which built and operates the Z facility, is the sole representative from a nuclear weapons lab in a new Department of Energy leadership program that recently visited Sandia.

ORNL, HTS International Corporation to Collaborate on Manufacturing Research

HTS International Corporation and the Department of Energy's Oak Ridge National Laboratory have signed an agreement to explore potential collaborations in advanced manufacturing research.

Jefferson Lab Director Honored with Energy Secretary Award

Hugh Montgomery, director of the Department of Energy's Thomas Jefferson National Accelerator Facility (Jefferson Lab), was awarded The Secretary's Distinguished Service Award by the Secretary of Energy earlier this year.

New Projects to Make Geothermal Energy More Economically Attractive

Geothermal energy, a clean, renewable source of energy produced by the heat of the earth, provides about 6 percent of California's total power. That number could be much higher if associated costs were lower. Now scientists at the Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) have launched two California Energy Commission-funded projects aimed at making geothermal energy more cost-effective to deploy and operate.

Southern Research Project Advances Novel CO2 Utilization Strategy

The U.S. Department of Energy's Office of Fossil Energy has awarded Southern Research nearly $800,000 for a project that targets a more cost-efficient and environmentally friendly method of producing some of the most important chemicals used in manufacturing.

Harker School Wins 2017 SLAC Regional Science Bowl Competition

After losing its first match of the day to the defending champions, The Harker School's team won 10 consecutive rounds to claim victory in the annual SLAC Regional DOE Science Bowl on Saturday, Feb. 11.

Francis Alexander Named Deputy Director of Brookhaven Lab's Computational Science Initiative

Alexander brings extensive management and leadership experience in computational science research to the position.

Kalinin, Paranthaman Elected Materials Research Society Fellows

Two researchers at Oak Ridge National Laboratory, Sergei Kalinin and Mariappan Parans Paranthaman, have been elected fellows of the Materials Research Society.

Two PNNL Researchers Elected to Membership in the National Academy of Engineering

Two scientists at the Pacific Northwest National Laboratory will become members of the prestigious National Academy of Engineering.


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Modeling the "Flicker" of Gluons in Subatomic Smashups

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Rare Nickel Atom Has "Doubly Magic" Structure

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Microbial Activity in the Subsurface Contributes to Greenhouse Gas Fluxes

Natural carbon dioxide production from deep subsurface soils contributes significantly to emissions, even in a semiarid floodplain.

Stretching a Metal Into an Insulator

Straining a thin film controllably allows tuning of the materials' magnetic, electronic, and catalytic properties, essential for new energy and electronic devices.

How Moisture Affects the Way Soil Microbes Breathe

Study models soil-pore features that hold or release carbon dioxide.

ARM Data Is for the Birds

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The Future of Coastal Flooding

Better storm surge prediction capabilities could help reduce the impacts of extreme weather events, such as hurricanes.

Estimating Global Energy Use for Water-Related Processes

Scientists find that water-related energy consumption is increasing across the globe, with pronounced differences across regions and sectors.


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Fats Into Jet Fuel: NC State Develops Biofuels Technology

Article ID: 527706

Released: 2007-02-28 15:20:00

Source Newsroom: North Carolina State University

Media Contacts:

Mick Kulikowski, News Services, 919/515-3470

Feb. 28, 2007

FOR IMMEDIATE RELEASE

New biofuels technology developed by North Carolina State University engineers has the potential to turn virtually any fat source " vegetable oils, oils from animal fat and even oils from algae " into fuel to power jet airplanes.

The technology " called Centiaâ„¢, which is derived from "crudus potentia," or "green power" in Latin " is "100 percent green," as no petroleum-derived products are added to the process. Centiaâ„¢ can also be used to make additives for cold-weather biodiesel fuels and holds the potential to fuel automobiles that currently run on gasoline.

NC State received provisional patents to use the process to convert fats into jet fuel or additives for cold-weather biodiesel fuels. The technology has been licensed by Diversified Energy Corp., a privately held Arizona company specializing in the development of advanced alternative and renewable energy technologies and projects.

Dr. William Roberts, professor of mechanical and aerospace engineering and director of the Applied Energy Research Laboratory at NC State, developed the biofuels process with NC State's Dr. Henry Lamb, associate professor of chemical and biomolecular engineering; Dr. Larry Stikeleather, professor of biological and agricultural engineering; and Tim Turner of Turner Engineering in Carrboro, N.C.

Roberts says that besides being "100 percent green," the new technology has some key advantages over other biofuel projects.

"We can take virtually any lipid-based feedstock, or raw material with a fat source " including what is perceived as low-quality feedstock like cooking grease " and turn it into virtually any fuel," Roberts says. "Using low-quality feedstock is typically 30 percent less costly than using corn or canola oils to make fuel. And we're not competing directly with the food supply, like ethanol-based fuels that are made from corn."

The fuel created by the new process also burns cleaner, so it's better for the environment, Roberts says. There is no soot or particulate matter associated with fuel from fats.

Further, Roberts says, the Centiaâ„¢ process puts to use what other biodiesel processes throw away. Converting feedstock into fuel produces a low-value commodity " glycerol " as a by-product. Rather than discarding glycerol as waste like most biodiesel plants do, the NC State engineers' process burns glycerol cleanly and efficiently to provide some of the process' requisite high temperatures.

"Instead of composting the glycerol as waste, we use it as an integral part of the fuel-making process," Roberts said.

It really does take a rocket scientist to make jet fuel, especially out of oils or agricultural crops, Roberts says. The physical and chemical properties of traditional biodiesel fuels " their combustion characteristics and viscosity, for example " don't match the stringent requirements required of jet fuels, making biodiesel unacceptable for the task.

"Jet fuel travels at 25,000 to 35,000 feet where temperatures can reach 70 degrees below zero Fahrenheit, so it needs to flow better in cold temperatures," Roberts says.

The Centiaâ„¢ process comprises four steps, Roberts explains. First, the engineers use high temperatures and high water pressure to strip off the so-called free fatty acids from the accumulated feedstock of oils and fats, or triglycerides. Next, the engineers place the free fatty acids in a reactor to perform the decarboxylation step; that is, carbon dioxide is taken off the free fatty acids. Depending on the feedstock used, the scientists are left with alkanes, or straight-chain hydrocarbons of either 15 or 17 carbon atoms.

"After these first two steps, which are always the same no matter which fuel you want, we can make any fuel we want to make," Roberts says. "In the last two steps, we can change the recipe based on the fuel output desired."

In the last two steps, the engineers break up the straight chains into molecules with branches, making them more compact and changing their chemical and physical characteristics. Jet fuel and biodiesel fuel require a mixture of molecules with between 10 and 14 carbon atoms, while gasoline requires only eight carbon atoms, so the engineers can control the process to elicit exactly the type of fuel they desire.

Finally, the engineers make some other chemical tweaks to create the desired fuel. Also, the glycerol by-product is burned off to provide heat for the various processes involved.

"We produce one-and-a-half billion gallons of animal fats annually, which is about half of the amount of vegetable oil produced yearly," Roberts said. "Animal fats are harder to work with, but cheaper. Last year, for the first time ever, fuel costs in the aviation industry exceeded labor costs. We think the aviation industry is keen on finding alternatives to petroleum-based jet fuel."

Dr. Bill Roberts, 919/515-5294

- kulikowski -