Doe Science news source
The DOE Science News Source is a Newswise initiative to promote research news from the Office of Science of the DOE to the public and news media.
  • 2017-05-01 18:05:55
  • Article ID: 673921

Teaching Perovskites to Swim

A two-component layer protects a sunlight-harvesting device from water and heat

  • Credit: Image: Rebecca Palmer, ANSER EFRC

    The perovskite device is made of different layers, each of which has a specific function. Together, the titanium dioxide and PC61BM layers protect the perovskite from heat and water.

  • Credit: Image: Nathan Johnson, Pacific Northwest National Lab

    Together, two simple layers protect promising materials called perovskites from water and heat, allowing the material to turn sunlight into electricity.

Harvesting sunlight and using it to power our homes and devices is a reality today. Generally, most commercial solar cells are made of silicon. However, as highlighted previously, a type of material called perovskite halides are a potential competitor of silicon. Unfortunately, most perovskite halides are sensitive to moisture and high temperatures such that exposure to either will quickly degrade these materials — rendering them useless. Researchers at the Argonne-Northwestern Solar Energy Research Center (ANSER) have developed a way to protect perovskites from water and stabilize them against heat. By carefully growing an ultrathin layer of metal oxide on a carbon coating, the researchers made a perovskite device that worked even after dousing the device with a stream of water.

Solar cells are made up of layers, each with a specific duty. The perovskite layer absorbs sunlight, which can excite an electron. The electron could go right back to where it started, unless it can be extracted out of the absorbing layer quickly. For this device, the researchers placed a layer of PC61BM, a carbon-based material, on top of the perovskite, which has two roles. First, PC61BM is good at extracting electrons once they are excited by sunlight. Second, the PC61BM layer protects the perovskite from water vapor, which is one of the reactants used for forming the final protective coating  — titanium dioxide.

The titanium dioxide layer was grown using atomic layer deposition (ALD), a method that deposits alternating layers of titanium and oxygen atoms. The researchers demonstrated that depositing the titanium dioxide by ALD creates a barrier with no pinholes, effectively blocking moisture from entering the film. Only about 20 nanometers of titanium dioxide on the PC61BM were needed to protect the perovskite. This layer is around 1,000 times thinner than the thickness of a human hair.

On top of the titanium dioxide, aluminum electrodes were deposited and protected by a thin layer of gold. On the opposite side of the perovskite, the team placed a nickel oxide layer that is good at extracting the positively charged holes left by the electrons. Glass, coated with a conductive film, is used as a support that allows light to pass through and a circuit to be formed.

The device held up to pure water and a temperature of 100 °C (around 200 °F) thanks to the titanium dioxide layer. In Soo Kim, a postdoctoral fellow and lead researcher, explained that he was excited about this result. “The key challenge to commercialization of any halide perovskite-based devices is the environmental stability.”

Many people have been studying perovskite halides, but the stability under real-world environmental situations has been largely overlooked. Kim's work is one of the first examples of protecting perovskite from liquid water with an ultrathin metal oxide layer. Alex Martinson, who directed the work, said, “It is surprising when something simple works so well.”

Martinson explained that perovskite solar cells have a lot of promise because they have the potential to be cheaper than the current commercial devices, such as silicon. The silicon manufacturing process is energy intensive, and silicon materials are required to be highly pure. In contrast, there are many pathways to make perovskites, and the performance of perovskite devices are less sensitive to impurities. Scientists at ANSER are excited to continue to explore what perovskites can do. Enabling these devices to withstand water and heat is a big step towards being able to buy a perovskite device at a local hardware store.

Acknowledgments: 

This work was supported as part of the Argonne-Northwestern Solar Energy Research Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. This work made use of the Pulsed Laser Deposition Shared Facility at the Materials Research Center at Northwestern University supported by the National Science Foundation’s Materials Research Science and Engineering Centers program. D.H.C. acknowledges support from the Link Foundation through the Link Foundation Energy Fellowship Program. Use of the Center for Nanoscale Materials, a U.S. Department of Energy Office of Science user facility, was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

More Information: 

Kim IS, DH Cao, DB Buchholz, JD Emery, OK Farha, JT Hupp, MG Kanatzidis, and ABF Martinson. 2016. "Liquid Water- and Heat-Resistant Hybrid Perovskite Photovoltaics via an Inverted ALD Oxide Electron Extraction Layer Design." Nano Letters 16(12):7786-7790. DOI: 10.1021/acs.nanolett.6b03989

This item, written by Rebecca Palmer, is part of Frontiers in Energy Research, a newsletter for the Energy Frontier Research Centers created by early career members of the centers. See http://www.energyfrontier.us/newsletter/

X
X
X
  • Filters

  • × Clear Filters

Nanoparticle Supersoap Creates 'Bijel' With Potential as Sculptable Fluid

A new type of "bijel" created by Berkeley Lab scientists could one day lead to applications in soft robotics, liquid circuitry, and energy conversion.

With Extra Sugar, Leaves Get Fat Too

Eat too much without exercising and you'll probably put on a few pounds. As it turns out, plant leaves do something similar. In a new study at the U.S. Department of Energy's Brookhaven National Laboratory, scientists show that retaining sugars in plant leaves can make them get fat too. In plants, this extra fat accumulation could be a good thing.

High-Speed Movie Aids Scientists Who Design Glowing Molecules

In a recent experiment conducted at the Department of Energy's SLAC National Accelerator Laboratory, a research team used bright, ultrafast X-ray pulses from SLAC's X-ray free-electron laser to create a high-speed movie of a fluorescent protein in action. With that information, the scientists began to design a marker that switches more easily, a quality that can improve resolution during biological imaging.

Biomass-Produced Electricity in the US Possible, but It'll Cost

If the U.S. wants to start using wood pellets to produce energy, either the government or power customers will have to pay an extra cost, a new University of Georgia study has found.

Scientists Make Atoms-Thick Post-It Notes for Solar Cells and Circuits

In a study published Sept. 20 in Nature, UChicago and Cornell University researchers describe an innovative method to make stacks of semiconductors just a few atoms thick. The technique offers scientists and engineers a simple, cost-effective method to make thin, uniform layers of these materials, which could expand capabilities for devices from solar cells to cell phones.

Titan Helps Researchers Suck Mystery Out of Cell's 'Vacuum Cleaners'

In cancer cells, a membrane transport protein called P-glycoprotein, or Pgp, actively pumps anticancer drugs out of the cell, contributing to multidrug resistance. Recently, a team led by computational biophysicist Emad Tajkhorshid from the University of Illinois at Urbana-Champaign (UIUC) used the Titan supercomputer to uncover new details about Pgp that could help the drug discovery community manipulate Pgp function.

Laser-Free Method of Ion Cooling Has Range of Potential Uses

Prof. Daniel Zajfman's universal ion trap cools to a tenth of a degree above absolute zero. The new method does not depend on the type or the weight of the ion and, thus, might be used to investigate the properties of large biological molecules or nanoparticles, among other things.

Tiny Lasers from a Gallery of Whispers

Whispering gallery mode resonators rely on a phenomenon similar to an effect observed in circular galleries, and the same phenomenon applies to light. When light is stored in ring-shaped or spherical active resonators, the waves superimpose in such a way that it can result in laser light. This week in APL Photonics, investigators report a new type of dye-doped WGM micro-laser that produces light with tunable wavelengths.

Copper Catalyst Yields High Efficiency CO2-to-Fuels Conversion

Berkeley Lab scientists have developed a new electrocatalyst that can directly convert carbon dioxide into multicarbon fuels and alcohols using record-low inputs of energy. The work is the latest in a round of studies coming out of Berkeley Lab tackling the challenge of a creating a clean chemical manufacturing system that can put carbon dioxide to good use.

Solar-to-Fuel System Recycles CO2 to Make Ethanol and Ethylene

Berkeley Lab scientists have harnessed the power of photosynthesis to convert carbon dioxide into fuels and alcohols at efficiencies far greater than plants. The achievement marks a significant advance in the effort to move toward sustainable sources of fuel.


  • Filters

  • × Clear Filters

PPPL Physicist Francesca Poli Named ITER Scientist Fellow

Article describes new ITER Scientist Fellow.

Los Alamos Gains Role in High-Performance Computing for Materials Program

A new high-performance computing initiative announced this week by the U.S. Department of Energy will help U.S. industry accelerate the development of new or improved materials for use in severe environments.

UK Commits $88 Million to LBNF/DUNE in First-Ever Umbrella Science Agreement with U.S.

The UK has committed $88 million to the Long-Baseline Neutrino Facility and Deep Underground Neutrino Experiment as part of an umbrella science and technology agreement with the United States.

Wayne State Receives $1.2 Million NSF Grant to Develop Autonomous Battery Operating System

Researchers at Wayne State University led by Nathan Fisher, associate professor of computer science in the College of Engineering, received a $1.2 million grant from the National Science Foundation to address the need for effective, integrative battery operating systems that provide sustained and reliable power.

UAH leads effort that secures $20 million grant from the National Science Foundation

A partnership comprising nine universities in Alabama, including The University of Alabama in Huntsville (UAH) as the lead institution, has been awarded a $20 million, five-year grant by the National Science Foundation's Experimental Program to Stimulate Competitive Research (EPSCoR).

Sandia Labs Wins 5 Regional Technology Transfer Awards

Sandia National Laboratories won five awards from the 2017 Federal Laboratory Consortium for its work to develop and commercialize innovative technologies.

Tulane Receives Grant to Reduce Auto Emissions

Members of Tulane University's Shantz Lab will work with industrial scientists to assist in the development of next-generation materials designed to reduce harmful automotive emissions. The three-year old lab and its group of students have received a grant and equipment resources from SACHEM, Inc., a chemical science company.

Lab Leads New Effort in Materials Development

Lawrence Livermore National Lab will be part of a multi-lab effort to apply high-performance computing to US-based industry's discovery, design, and development of materials for severe environments under a new initiative announced by the Department of Energy (DOE) on Sept. 19.

ORNL Innovation Crossroads Program Opens Second Round of Energy Entrepreneurial Fellowships

Entrepreneurs are invited to apply for the second round of Oak Ridge National Laboratory's Innovation Crossroads program.

Los Alamos Recognized as Top Diversity Employer

For the second straight year, Los Alamos National Laboratory was recognized as a top diversity employer by LATINA Style and STEM Workforce Diversity magazine.


  • Filters

  • × Clear Filters

Fungi: Gene Activator Role Discovered

Specific modifications to fungi DNA may hold the secret to turning common plant degradation agents into biofuel producers.

First Look at a Living Cell Membrane

Neutrons provide the solution to nanoscale examination of living cell membrane and confirm the existence of lipid rafts.

High Yield Biomass Conversion Strategy Ready for Commercialization

Researchers convert 80 percent of biomass into high-value products with strategy that's ready for commercialization.

Consequences of Drought Stress on Biofuels

Switchgrass cultivated during a year of severe drought inhibited microbial fermentation and resulting biofuel production.

Clay Minerals and Metal Oxides Change How Uranium Travels Through Sediments

Montmorillonite clays prevent uranium from precipitating from liquids, letting it travel with groundwater.

Tundra Loses Carbon with Rapid Permafrost Thaw

Seven-year-study shows plant growth does not sustainably balance carbon losses from solar warming and permafrost thaw.

Crystals Grow by Twisting, Aligning and Snapping Together

Van der Waals force, which that enables tiny crystals to grow, could be used to design new materials.

Vitamin B12 Fuels Microbial Growth

Scarce compound, vitamin B12, is key for cellular metabolism and may help shape microbial communities that affect environmental cycles and bioenergy production.

Carbon in Floodplain Unlikely to Cycle into the Atmosphere

Microbes leave a large fraction of carbon in anoxic sediments untouched, a key finding for understanding how watersheds influence Earth's ecosystem.

Bacterial Cell Wall Changes Produce More Fatty Molecules

New strategy greatly increases the production and secretion of biofuel building block lipids in bacteria able to grow at industrial scales.


Spotlight

Thursday September 21, 2017, 03:05 PM

From Science to Finance: SLAC Summer Interns Forge New Paths in STEM

SLAC National Accelerator Laboratory

Thursday September 07, 2017, 02:05 PM

Students Discuss 'Cosmic Opportunities' at 45th Annual SLAC Summer Institute

SLAC National Accelerator Laboratory

Thursday August 31, 2017, 05:05 PM

Binghamton University Opens $70 Million Smart Energy Building

Binghamton University, State University of New York

Wednesday August 23, 2017, 05:05 PM

Widening Horizons for High Schoolers with Code

Argonne National Laboratory

Saturday May 20, 2017, 12:05 PM

Rensselaer Polytechnic Institute Graduates Urged to Embrace Change at 211th Commencement

Rensselaer Polytechnic Institute (RPI)

Monday May 15, 2017, 01:05 PM

ORNL, University of Tennessee Launch New Doctoral Program in Data Science

Oak Ridge National Laboratory

Friday April 07, 2017, 11:05 AM

Champions in Science: Profile of Jonathan Kirzner

Department of Energy, Office of Science

Wednesday April 05, 2017, 12:05 PM

High-Schooler Solves College-Level Security Puzzle From Argonne, Sparks Interest in Career

Argonne National Laboratory

Tuesday March 28, 2017, 12:05 PM

Champions in Science: Profile of Jenica Jacobi

Department of Energy, Office of Science

Friday March 24, 2017, 10:40 AM

Great Neck South High School Wins Regional Science Bowl at Brookhaven Lab

Brookhaven National Laboratory

Wednesday February 15, 2017, 04:05 PM

Middle Schoolers Test Their Knowledge at Science Bowl Competition

Argonne National Laboratory

Friday January 27, 2017, 04:00 PM

Haslam Visits ORNL to Highlight State's Role in Discovering Tennessine

Oak Ridge National Laboratory

Tuesday November 08, 2016, 12:05 PM

Internship Program Helps Foster Development of Future Nuclear Scientists

Oak Ridge National Laboratory

Friday May 13, 2016, 04:05 PM

More Than 12,000 Explore Jefferson Lab During April 30 Open House

Thomas Jefferson National Accelerator Facility

Monday April 25, 2016, 05:05 PM

Giving Back to National Science Bowl

Ames Laboratory

Friday March 25, 2016, 12:05 PM

NMSU Undergrad Tackles 3D Particle Scattering Animations After Receiving JSA Research Assistantship

Thomas Jefferson National Accelerator Facility

Tuesday February 02, 2016, 10:05 AM

Shannon Greco: A Self-Described "STEM Education Zealot"

Princeton Plasma Physics Laboratory

Monday November 16, 2015, 04:05 PM

Rare Earths for Life: An 85th Birthday Visit with Mr. Rare Earth

Ames Laboratory

Tuesday October 20, 2015, 01:05 PM

Meet Robert Palomino: 'Give Everything a Shot!'

Brookhaven National Laboratory

Tuesday April 22, 2014, 11:30 AM

University of Utah Makes Solar Accessible

University of Utah

Wednesday March 06, 2013, 03:40 PM

Student Innovator at Rensselaer Polytechnic Institute Seeks Brighter, Smarter, and More Efficient LEDs

Rensselaer Polytechnic Institute (RPI)

Friday November 16, 2012, 10:00 AM

Texas Tech Energy Commerce Students, Community Light up Tent City

Texas Tech University

Wednesday November 23, 2011, 10:45 AM

Don't Get 'Frosted' Over Heating Your Home This Winter

Temple University

Wednesday July 06, 2011, 06:00 PM

New Research Center To Tackle Critical Challenges Related to Aircraft Design, Wind Energy, Smart Buildings

Rensselaer Polytechnic Institute (RPI)

Friday April 22, 2011, 09:00 AM

First Polymer Solar-Thermal Device Heats Home, Saves Money

Wake Forest University

Friday April 15, 2011, 12:25 PM

Like Superman, American University Will Get Its Energy from the Sun

American University

Thursday February 10, 2011, 05:00 PM

ARRA Grant to Help Fund Seminary Building Green Roof

University of Chicago

Tuesday December 07, 2010, 05:00 PM

UC San Diego Installing 2.8 Megawatt Fuel Cell to Anchor Energy Innovation Park

University of California San Diego

Monday November 01, 2010, 12:50 PM

Rensselaer Smart Lighting Engineering Research Center Announces First Deployment of New Technology on Campus

Rensselaer Polytechnic Institute (RPI)

Friday September 10, 2010, 12:40 PM

Ithaca College Will Host Regional Clean Energy Summit

Ithaca College

Tuesday July 27, 2010, 10:30 AM

Texas Governor Announces $8.4 Million Award to Create Renewable Energy Institute

Texas Tech University

Friday May 07, 2010, 04:20 PM

Creighton University to Offer New Alternative Energy Program

Creighton University

Wednesday May 05, 2010, 09:30 AM

National Engineering Program Seeks Subject Matter Experts in Energy

JETS Junior Engineering Technical Society

Wednesday April 21, 2010, 12:30 PM

Students Using Solar Power To Create Sustainable Solutions for Haiti, Peru

Rensselaer Polytechnic Institute (RPI)

Wednesday March 03, 2010, 07:00 PM

Helping Hydrogen: Student Inventor Tackles Challenge of Hydrogen Storage

Rensselaer Polytechnic Institute (RPI)

Thursday February 04, 2010, 02:00 PM

Turning Exercise into Electricity

Furman University

Thursday November 12, 2009, 12:45 PM

Campus Leaders Showing the Way to a Sustainable, Clean Energy Future

National Wildlife Federation (NWF)

Tuesday November 03, 2009, 04:20 PM

Furman University Receives $2.5 Million DOE Grant for Geothermal Project

Furman University

Thursday September 17, 2009, 02:45 PM

Could Sorghum Become a Significant Alternative Fuel Source?

Salisbury University

Wednesday September 16, 2009, 11:15 AM

Students Navigating the Hudson River With Hydrogen Fuel Cells

Rensselaer Polytechnic Institute (RPI)

Wednesday September 16, 2009, 10:00 AM

College Presidents Flock to D.C., Urge Senate to Pass Clean Energy Bill

National Wildlife Federation (NWF)

Wednesday July 01, 2009, 04:15 PM

Northeastern Announces New Professional Master's in Energy Systems

Northeastern University

Friday October 12, 2007, 09:35 AM

Kansas Rural Schools To Receive Wind Turbines

Kansas State University

Thursday August 17, 2006, 05:30 PM

High Gas Prices Here to Stay, Says Engineering Professor

Rowan University

Wednesday May 17, 2006, 06:45 PM

Time Use Expert's 7-Year Fight for Better Gas Mileage

University of Maryland, College Park





Showing results

0-4 Of 2215